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Phosphine Organocatalysis [PDF]
Chemical Reviews, 2018 The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a phosphine to an electrophilic starting material, producing a reactive zwitterionic intermediate, generally under mild conditions. In this Review, we classify nucleophilic phosphine catalysis reactions in terms of their electrophilic components. In the majority of
Hongchao Guo +4 more
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CONFIRMATION OF CIRCUMSTELLAR PHOSPHINE [PDF]
The Astrophysical Journal, 2014 Accepted for publication in ApJ ...
Marcelino Agúndez +5 more
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Mechanisms of Phosphine Toxicity [PDF]
Journal of Toxicology, 2011 Fumigation with phosphine gas is by far the most widely used treatment for the protection of stored grain against insect pests. The development of high-level resistance in insects now threatens its continued use.
Nisa S. Nath +4 more
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Coordination chemistry with phosphine and phosphine oxide-substituted hydroxyferrocenes
Dalton Transactions, 2010 New unsymmetrical hydroxyferrocenes were synthesised from dibromoferrocene. The oxygen heteroatom was introduced via lithiation and quenching with bis-trimethylsilylperoxide followed by hydrolysis to unmask the hydroxyl functionality. The coordination chemistry of 1'-(diphenylphosphino)-1-hydroxyferrocene 2 was explored with palladium and rhodium ...
Atkinson, RCJ +3 more
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Fayixue Zazhi, 2022 ObjectiveTo study the distribution of total phosphine in phosphine poisoning victims and summarize the characteristics of phosphine poisoning cases.MethodsThe phosphine and its metabolites in the biological samples of 29 victims in 16 phosphine poisoning
YAN Hui +6 more
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Responses of phosphate transporter gene and alkaline phosphatase in Thalassiosira pseudonana to phosphine. [PDF]
PLoS ONE, 2013 Phosphine, which is released continuously from sediment, can affect the eco-physiological strategies and molecular responses of phytoplankton. To examine the effects of phosphine on phosphorus uptake and utilization in Thalassiosira pseudonana, we ...
Mei Fu +3 more
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Pesticidal Toxicity of Phosphine and Its Interaction with Other Pest Control Treatments
Current Issues in Molecular Biology, 2023 Phosphine is the most widely used fumigant for stored grains due to a lack of better alternatives, all of which have serious shortcomings that restrict their use.
Saad M. Alzahrani, Paul R. Ebert
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Insects, 2023 Knowledge about resistance mechanisms can provide ideas for pesticide resistance management. Although several studies have unveiled the positive or negative impacts of gut microbes on host pesticide resistance, minimal research is available regarding the
Zhengyan Wang +4 more
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Comparative toxicity of fumigants and a phosphine synergist using a novel containment chamber for the safe generation of concentrated phosphine gas. [PDF]
PLoS ONE, 2006 With the phasing out of ozone-depleting substances in accordance with the United Nations Montreal Protocol, phosphine remains as the only economically viable fumigant for widespread use.
Nicholas Valmas, Paul R Ebert
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Insects, 2022 Insects rely on lipids as an energy source to perform various activities, such as growth, flight, diapause, and metamorphosis. This study evaluated the role of lipids in phosphine resistance by stored-grain insects.
Ihab Alnajim +5 more
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