Atroposelective Suzuki–Miyaura Coupling to Form 2‐Amino‐2′‐Hydroxybiphenyls Enabled by sRuPhos
We report a new chiral phosphine ligand, sRuPhos, which permits the highly enantioselective Suzuki–Miyaura coupling of ortho‐aniline and ortho‐phenol building blocks. This results in 2‐amino‐2′‐hydroxybiphenyls with very high enantiomeric excesses, products that will have application in pharmaceutical synthesis and ligand design for catalysis ...
Hamzah Sharif +3 more
wiley +2 more sources
Phosphorus cycling through phosphine in paddy fields
Shenghui Han +3 more
openalex +2 more sources
Functionalised phosphines - Fascinating multidentate ligands for luminescent Zn(II) and Cu(I) complexes [PDF]
Sarah Linert
openalex +1 more source
Stretchable Energy Storage with Eutectic Gallium Indium Alloy
A highly stretchable liquid metal‐based electrode is developed via a one‐step process, retaining conductivity and capacitance after mechanical deformation up to 900% strain. The stretchable all‐solid‐state device provides a areal energy density of 43 µWh cm⁻2 after 150% strain.
Adit Gupta +6 more
wiley +1 more source
Synthesis and Characterization of Unusual S=1 Fe(0)‐Silyl Complexes Supported by Styrene Ligands
Despite the long‐standing importance of iron‐silicon bonds as related to catalysis, high‐spin Fe(0)‐silyl complexes remain a historical synthetic challenge in the field. Herein, we report the first series of high‐spin S = 1, styrene‐stabilized Fe(0)‐silyl complexes followed by extensive characterization via Mössbauer spectroscopy, single crystal X‐ray ...
Alexis K. Bauer +2 more
wiley +2 more sources
Three Dimensional Printing of Bioinspired Composite Aerogels for Solar Steam Generation
Freshwater scarcity demands efficient purification strategies. Inspired by desert grasses, reduced graphene oxide‐doped polyacrylamide aerogels with longitudinal grooves are fabricated via high‐speed three‐dimensional printing and freeze‐drying. The biomimetic design enables dual‐mode water transport, achieving a capillary flow of 2.16 cm in 10 minutes
Luyang Liu +7 more
wiley +1 more source
(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications
In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh +5 more
wiley +2 more sources
Organophosphorus-induced neurotoxicity in the absence of neuropathy target esterase inhibition: the effects of triphenyl phosphine in the European ferret [PDF]
S L Davis
openalex +1 more source
Two‐photon polymerization enables high‐resolution microfabrication, but performing alignment when printing multiple structures is difficult. Here, we present a fast, robust, and open‐source protocol for automated alignment on Nanoscribe systems. Achieving ≈0.4 μm accuracy in under 5 s, our protocol reduces time and error in multimaterial printing. This
Daniel Maher +4 more
wiley +1 more source
New push–pull para‐azaquinodimethane derivatives were synthetized through a sustainable protocol. Transient absorption results showed ultrafast intermolecular singlet fission (SF) in film and demonstrated for AsOMe higher triplet energy than for literature SF materials, with intriguing perspectives for photovoltaics toward silicon matched SF.
Martina Alebardi +11 more
wiley +2 more sources

