Activation and Derivatization of Perfluoro(methyl Vinyl Ether) by a Rh(I) Germyl Complex
European Journal of Inorganic Chemistry, EarlyView.Treatment of the rhodium (I) germyl complex [Rh(GePh3)(PEt3)3] with perfluoro(methyl vinyl ether) [PMVE] resulted in CO and CF bond cleavage and decarbonylation reactions, to yield trans‐[Rh(CFCF2)(CO)(PEt3)2] and germylated species including fluorogermane FGePh3, and fluoroalkene CF(GePh3)CF2.
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Fluorogenic Coumarins Activated via Bioorthogonal Reactions. [PDF]
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Non-spectator behavior of a neutral phosphine ligand driven by a redox-active boron cluster. [PDF]
Chem SciRiffle JR +4 more
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One-pot organocatalysis of diacrylates to functional polyesters for toughening polylactide. [PDF]
Natl Sci RevZhao Y, Meng W, Chen EY, Tang X.
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Heavyweight Champion: Caesium Diorganophosphides Outperform Lighter Congeners in the Catalytic Hydrophosphination of Alkenes and Alkynes. [PDF]
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The versatile synthesis and biological evaluation of all-alkyl biscationic quaternary phosphonium compounds: atom-economical and potent disinfectants. [PDF]
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