Results 161 to 170 of about 38,475 (330)

Application of Monodentate Secondary Phosphine Oxides, a New Class of Chiral Ligands, in Ir(I)-Catalyzed Asymmetric Imine Hydrogenation [PDF]

open access: green, 2003
Xiaobin Jiang   +7 more
openalex   +1 more source

Deposition and characterization of PECVD phosphorus doped silicon oxynitride layers for integrated optics applications [PDF]

open access: yes, 2005
Phosphorus-doped silicon oxynitride layers have been deposited by a Plasma Enhanced Chemical Vapor Deposition process from $N_20$, 2% $SiH_4/N_2$ and 5% $PH_3/Ar$ gaseous mixtures.
Driessen, A.   +3 more
core   +1 more source

Piano‐Stool Rhodium(V) and Rhodium(IV) Intermediates in C─H Functionalization and B─H Functionalization: Mechanistic Insights and Emerging Reactivity

open access: yesAsian Journal of Organic Chemistry, EarlyView.
High‐valent Rh(IV) and Rh(V) species have been invoked to rationalize enhanced catalytic reactivity. This review examines evidence for both, emphasizing reactions proceeding through the Rh(III)/Rh(IV)/Rh(II) cycle. While Rh(V) intermediates are computationally supported, experimental evidence is limited; Rh(IV) species are supported by both theory and ...
Yujie Cao, Arnav Kacker, Kevin G. M. Kou
wiley   +1 more source

Molecular Design and Synthesis of Narrowband Near‐Ultraviolet and Pure Deep‐Blue Thermally Activated Delayed Fluorescence Materials by an Ether Group Strategy

open access: yesAngewandte Chemie, EarlyView.
Directed tri‐ortho‐lithiation–borylation reactions produced a new family of N,N‐bridge‐type triphenylboranes that bear ether groups at two ortho positions relative to the boron center. The ether groups enable the fine‐tuning of the HOMO and LUMO energy gap, leading to narrowband near‐ultraviolet and pure deep‐blue thermally activated delayed ...
Yuichi Kitamoto   +8 more
wiley   +2 more sources

Asymmetric Synthesis of 2H‐Azirines Derived from Phosphine Oxides Using Solid‐Supported Amines. Ring Opening of Azirines with Carboxylic Acids. [PDF]

open access: green, 2003
Francisco Palácios   +5 more
openalex   +1 more source

Reductive N2 Cleavage and Nitride Insertion Reactivity at Molybdenum Complexes Supported by a Rigid PNP Pincer

open access: yesAngewandte Chemie, EarlyView.
Reductive N2 cleavage at an acridane PNP pincer‐supported Mo center leads to the first crystallographically characterized example of an unusual Mo(IV) nitride species featuring a bridging N2 coordination stabilized via Mo‐N2 dπ‐pπ backbonding interactions. Nitride functionalization with CO leads to Mo(II) isocyanate species.
Minjun Kim   +8 more
wiley   +2 more sources

Deoxygenation of organic nitrites [PDF]

open access: yes
Organic nitrites deoxygenated in presence of tervalent phosphorus ...
Boyer, J. H., Woodyard, J. D.
core   +1 more source

The application of monodentate secondary phosphine oxide ligands in rhodium- and iridium-catalyzed asymmetric hydrogenation [PDF]

open access: green, 2004
Xiaobin Jiang   +4 more
openalex   +1 more source

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