Results 191 to 200 of about 76,679 (335)

Molecular Rotors as Reactivity Probes: Predicting Electrophilicity from the Speed of Rotation

open access: yesAngewandte Chemie, EarlyView.
A new empirical parameter, ERB, quantifies electrophilicity from rotational barriers of N‐phenylimide molecular rotors. ERB predicts reactivity trends in Michael additions, SN2, SNAr, Pd‐oxidative addition, and Sonogashira reactions by capturing both attractive and repulsive transition state interactions.
Hao Liu   +7 more
wiley   +2 more sources

Stuck on phosphines [PDF]

open access: yesNature Catalysis, 2020
openaire   +1 more source

Reductive N2 Cleavage and Nitride Insertion Reactivity at Molybdenum Complexes Supported by a Rigid PNP Pincer

open access: yesAngewandte Chemie, EarlyView.
Reductive N2 cleavage at an acridane PNP pincer‐supported Mo center leads to the first crystallographically characterized example of an unusual Mo(IV) nitride species featuring a bridging N2 coordination stabilized via Mo‐N2 dπ‐pπ backbonding interactions. Nitride functionalization with CO leads to Mo(II) isocyanate species.
Minjun Kim   +8 more
wiley   +2 more sources

Polymorphism in a secondary phosphine. [PDF]

open access: yesActa Crystallogr C Struct Chem
Liu M, Izod K, Waddell PG.
europepmc   +1 more source

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