Results 211 to 220 of about 76,679 (335)

One-pot synthesis of primary phosphines from white phosphorus.

Chem Commun (Camb)
Mende M, Cammarata J, Scott DJ, Wolf R.
europepmc   +1 more source

Au₁₄₇(SPh)₃₀(PPh₃)₁₂: A Geometrically Closed, but Electronically Open Triple-Shell Icosahedral Gold Cluster and its Geometrically Open Counterpart. [PDF]

Angew Chem Int Ed Engl
Strienz M, Poddelskii A, Moll BK, Schrenk C, Thomas PS, Clayborne AZ, Schnepf A.   +6 more
europepmc   +1 more source

Kinetic Study of the Intramolecular Decomposition of Some Phosphine N-Benzoyl Imines. [PDF]

, 1970
Gunnar Aksnes, Paul Frøyen, Terence Painter, Arne Haug, S. E. Rasmussen, Erling Sunde, Nils Andreas Sörensen   +6 more
openalex   +1 more source

A Homobimetallic Frustrated Lewis Pair Cobalt Catalyst for the Methanolysis of Hydrosilanes

Angewandte Chemie, EarlyView.
The bimetallic Co(I)/Co(–I) complex [Co(CO)2(κ3‐P,N,P‐PNHP)][Co(CO)4] shows excellent activities in the methanolysis of hydrosilanes, reaching TOF values of ca. 50 000 h−1. This behavior can be ascribed to the presence of the [Co(CO)4]– anion, which allows for a frustrated Lewis pair mechanism, resulting in a low energy pathway for the heterolytic ...
Ana Luque‐Gómez, Daniel Barrena‐Espés, Pilar García‐Orduña, Andrea Pérez‐García, Miguel A. Casado, Julen Munarriz, Manuel Iglesias   +6 more
wiley   +2 more sources

Asymmetric alkyl-alkyl coupling between electron-deficient and unactivated alkenes to access α-chiral phosphines by Ni catalysis. [PDF]

Sci Adv
Zou JY, Xing FL, Zi QX, Du HW, Chen M, Shu W.   +5 more
europepmc   +1 more source

Design of Aminophosphine Precursor for Robust Synthesis of InP Quantum Dots with Near‐unity Quantum Yield

Angewandte Chemie, EarlyView.
Alkylsiylamine‐based aminophosphine precursor was newly introduced to synthesize InP quantum dots (QDs). This new aminophosphine showed a faster reaction process compared to the conventional aminophosphine, resulting in the near‐unity quantum yield (QY) and a full‐width at half‐maximum of 48 nm without additional purification.
Doheon Yoo, Euk Hyun Kim, Ji‐Seoung Jeong, Ji Yeon Ryu, Sang Man Koo, Min‐Jae Choi   +5 more
wiley   +2 more sources

Synthesis of organophosphorus (III) compounds from white phosphorus enabled by a tandem electrothermal process. [PDF]

Natl Sci Rev
Feng K, Zhang H.
europepmc   +1 more source

Single‐Step Insertion of Organic Sulfur Into a Fe6C Carbide Carbonyl Cluster, Including the Natural Amino Acid L‐Cysteine: Vibrational Circular Dichroism and Chirality Transfer

Angewandte Chemie, EarlyView.
We describe a one‐pot synthetic procedure for the functionalization with organosulfur ligands of hexa‐iron carbide carbonyl clusters. This synthetic procedure is highly versatile and may be applied to alkyl, aryl, and functionalized organic sulfur reagents, including the chiral amino acids L‐ and D‐cysteine.
Francesca Forti, Andrea Pellegrini, Cristiana Cesari, Cristina Femoni, Maria Carmela Iapalucci, Michele Mancinelli, Stefano Zacchini   +6 more
wiley   +2 more sources

Unraveling the influence mechanisms of different substituents on the chemical activity of N-heterocyclic phosphines via theoretical calculations. [PDF]

J Mol Model
Chen Y.
europepmc   +1 more source

Reactivities of tertiary phosphines towards allenic, acetylenic, and vinylic Michael acceptors. [PDF]

Chem Sci
An F, Brossette J, Jangra H, Wei Y, Shi M, Zipse H, Ofial AR.   +6 more
europepmc   +1 more source