Lewis Acidity of the SbCl3/o‐chloranil System
Angewandte Chemie, EarlyView.An SbCl5 surrogate from easy‐to‐handle reagents! The putative SbCl3(o‐C6O2Cl4) synthon is calculated to be more Lewis acidic than SbCl5. Even if endergonic, its formation from SbCl3 and o‐chloranil can be driven by Lewis base coordination, leading to the corresponding adducts.
Ferit Şit +3 more
wiley +2 more sources
Acylphosphine Route to Colloidal InP Quantum Dots. [PDF]
J Am Chem SocStelmakh A +9 more
europepmc +1 more source
Catalysis by Phosphine Complexes of Silylruthenium Hydrides of the Addition of Carbon Tetrachloride to 1-Octene [PDF]
, 1978 Hideyuki Matsumoto +3 more
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A Bench‐Stable Fluorophosphine Nickel(0) Complex and Its Catalytic Application
Angewandte Chemie, EarlyView.We herein present the synthesis of a bench‐stable Ni(0) complex, [Ni(PFPh2)4], stabilized by vastly underexplored fluorophosphine ligands. The application of [Ni(PFPh2)4] in Suzuki–Miyaura and Kumada‐Tamao‐Corriu cross‐coupling reactions as well as in Buchwald–Hartwig C─N bond formation reactions, indicates its promising potential as alternative to ...
Franziska Flecken +3 more
wiley +2 more sources
Unraveling the influence mechanisms of different substituents on the chemical activity of N-heterocyclic phosphines via theoretical calculations. [PDF]
J Mol ModelChen Y.
europepmc +1 more source
NMR-Untersuchungen an Organoelement(IV b)-phosphinen,IV Phosphor-Zinn-Kopplungskonstanten von Trimethylstannylphosphinen und ihren Übergangsmetallcarbonylkomplexen / NMR-studies on Organoelement(IVb)-phosphines, IV Phosphorus-Tin Coupling Constants of Trimethyltin Phosphines and their Transition Metal Carbonyl Complexes [PDF]
, 1977 Herbert Schumann, Heinz‐Jürgen Kroth
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Taxonomy of Chemical Bondings: Opportunities and Challenges
Angewandte Chemie, EarlyView.The recent focus on supramolecular and nanosized systems produced a major increase in the types of observed noncovalent interactions and in the diversity of terms used to designate them. A hierarchical categorization (taxonomy) of terms used to designate electrophile···nucleophile interactions is proposed here.
Andrea Pizzi +5 more
wiley +2 more sources
Activation of perfluoro(methyl vinyl ether) at Rh(i) complexes: metal-centered <i>versus</i> phosphine-mediated decarbonylation. [PDF]
Chem SciMollasalehi S, Ahrens M, Braun T.
europepmc +1 more source
Metal nitrate complexes with tributyl phosphate and with trioctyl phosphine oxide
, 1963 Eugene Warren Nadig
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