Results 271 to 280 of about 51,028 (331)

Mechanistic Studies on Chalcogen-Atom Replacement Reactions of Phosphine Chalcogenides and Separation of the Intermediate Phosphine [PDF]

, 2008
MAJUMDER ARPI
core   +1 more source

Gold(I) Phosphine/Phosphido‐Borohydride Complexes

European Journal of Inorganic Chemistry, EarlyView.
Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair, Marc‐Etienne Moret, Luke A. Wilkinson, Adrian B. Chaplin   +3 more
wiley   +1 more source

Asymmetric alkyl-alkyl coupling between electron-deficient and unactivated alkenes to access α-chiral phosphines by Ni catalysis. [PDF]

Sci Adv
Zou JY, Xing FL, Zi QX, Du HW, Chen M, Shu W.   +5 more
europepmc   +1 more source

Activation and Derivatization of Perfluoro(methyl Vinyl Ether) by a Rh(I) Germyl Complex

European Journal of Inorganic Chemistry, EarlyView.
Treatment of the rhodium (I) germyl complex [Rh(GePh3)(PEt3)3] with perfluoro(methyl vinyl ether) [PMVE] resulted in CO and CF bond cleavage and decarbonylation reactions, to yield trans‐[Rh(CFCF2)(CO)(PEt3)2] and germylated species including fluorogermane FGePh3, and fluoroalkene CF(GePh3)CF2.
Soodeh Mollasalehi, Thomas Braun, Julie Borel   +2 more
wiley   +1 more source

Dynamic processes of the first NHC-substituted rhenium heptahydrides [ReH₇(NHC)₂].

Dalton Trans
Grieco G, Pierini A, Pierini M.
europepmc   +1 more source

Ligand Effects in Regio- and Enantioselective Cobalt-Catalyzed Intramolecular [4+2]- and [2+2]-Cycloaddition Reactions of Unactivated 1,3-Diene-8-ynes and 1,3-Diene-8-enes. [PDF]

Angew Chem Int Ed Engl
Ghosh KK, Chowdhury R, Gordon JP, RajanBabu TV.   +3 more
europepmc   +1 more source

PHOSPHINE

, 1964
Gokhale, S., Jolly, W.
openaire   +1 more source

Recent Developments in the Field of Air‐Stable Nickel(0) Precatalysts for Cross‐Coupling Reactions

European Journal of Inorganic Chemistry, EarlyView.
The development of bench‐stable Ni(0) sources aims to replace air‐sensitive [Ni(COD)2] (cod = cycloocta‐1,5‐diene) with easy‐to‐handle alternatives. Through a targeted ligand design, using electron‐deficient dienes, carbenes, and fluorophosphines, researchers have achieved air‐ and moisture‐tolerant complexes that show high catalytic activity in cross ...
Franziska Flecken, Schirin Hanf
wiley   +1 more source

Unraveling the influence mechanisms of different substituents on the chemical activity of N-heterocyclic phosphines via theoretical calculations. [PDF]

J Mol Model
Chen Y.
europepmc   +1 more source

Rigid Ligand Environments at Beryllium, From Spectroscopic Probes to Small Molecule Activation

European Journal of Inorganic Chemistry, EarlyView.
Due to the high rigidity and definition of beryllium scorpionate complexes, they can be used to study metal‐pseudohalide and ‐carbon bonds in detail. Furthermore, these compounds can be used to activate small molecules and exhibit unprecedented transmetalation reactions. In beryllium scorpionate complexes, three of the four available coordination sites
Magnus R. Buchner, Chantsalmaa Berthold
wiley   +1 more source