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Synthesis of primary phosphines from phosphine and arylethylenes
Russian Chemical Bulletin, 1995AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Boris A. Trofimov +6 more
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Differentially Substituted Phosphines via Decarbonylation of Acylphosphines.
Organic Letters, 2017A new route to phosphines was developed by a method that features a "pre-join and transform" process that proceeds via acylphosphine intermediates that may be readily prepared from carboxylic acids and disubstituted phosphines.
Rongrong Yu +3 more
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The chemical record, 2016
Our journey in organophosphorus research over the past 26 years is compiled in this Personal Account. Advances in palladacycle design have engendered a shift in our focus from template-mediated transformations to catalysis for the direct preparation of ...
R. J. Chew, P. Leung
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Our journey in organophosphorus research over the past 26 years is compiled in this Personal Account. Advances in palladacycle design have engendered a shift in our focus from template-mediated transformations to catalysis for the direct preparation of ...
R. J. Chew, P. Leung
semanticscholar +1 more source
2010
This chapter gives an account of the newer developments on the synthesis and reactivity of phosphine chalcogenides, mainly oxides and sulfides. A series of new synthetic methods for phosphine oxides is discussed, followed by preparations utilizing simple P-reagents such as P(iii)- and P(v)-chlorides, and >P(O)H species.
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This chapter gives an account of the newer developments on the synthesis and reactivity of phosphine chalcogenides, mainly oxides and sulfides. A series of new synthetic methods for phosphine oxides is discussed, followed by preparations utilizing simple P-reagents such as P(iii)- and P(v)-chlorides, and >P(O)H species.
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147-nm Photolysis of phosphine and phosphine-d3
The Journal of Physical Chemistry, 1981The 147-nm photodecompositions of PH/sub 3/ and PD/sub 3/ result in the formation of H/sub 2/ (D/sub 2/) and P/sub 2/H/sub 4/ (P/sub 2/D/sub 4/) in the gas phase and a solid deposit which is probably a mixture of phosphorous and polymeric phosphorous hydrides (PH)/sub x/ and (PD)/sub x/.
J. Blazejowski, F. W. Lampe
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, 2018
Although organophosphine syntheses have been known for the better part of a century, the synthesis of phosphines still represents an arduous task for even veteran synthetic chemists.
N. Rinehart, A. J. Kendall, D. R. Tyler
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Although organophosphine syntheses have been known for the better part of a century, the synthesis of phosphines still represents an arduous task for even veteran synthetic chemists.
N. Rinehart, A. J. Kendall, D. R. Tyler
semanticscholar +1 more source
(Ferrocenylmethyl)phosphine, an air-stable primary phosphine
Journal of the Chemical Society, Dalton Transactions, 1999Removal of formaldehyde from the readily prepared ferrocenyl (R) hydroxymethylphosphine RCH2P(CH2OH)2 with one mole equivalent of Na2S2O5 gave the completely air-stable primary phosphine RCH2PH2 as a crystalline, sublimable solid. With [Mo(CO)6] both mono-, [Mo(CO)5(RCH2PH2)], and di-substituted, [Mo(CO)4(RCH2PH2)2], products are readily formed, and ...
William Henderson +4 more
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Tertiary Amine-Mediated Reductions of Phosphine Oxides to Phosphines
Organic Letters, 2023The reduction of phosphine oxides without the use of highly reactive reductants represents a safer and more sustainable solution for recycling of organophosphorus compounds. Herein, we disclose an N,N,N',N'-tetramethylethylenediamine (TMEDA)-mediated reduction via an unusual intermolecular hydride transfer. Mechanistic studies suggest that TMEDA serves
Keshu Yin +4 more
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Phosphines: preparation, reactivity and applications
Organophosphorus Chemistry, 2018The annual survey of the literature relating to the chemistry of traditional phosphines containing only P–C and P–H bonds published during 2016 is presented.
A. Balueva, E. Musina, A. Karasik
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Microemulsions with Alkyldimethyl Phosphine Oxides and Alkyldiethyl Phosphine Oxides
Langmuir, 2008Alkyldimethyl phosphine oxides (C n DMPO) as well as alkyldiethyl phosphine oxides (C n DEPO) with chain lengths of n = 10 (decyl), 12 (dodecyl), and 14 (tetradecyl) were synthesized and purified to study how the formation of microemulsions depends on the size of the headgroup and on the length of the alkyl chain.
Reinhard Strey +2 more
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