Results 31 to 40 of about 48,864 (210)
New cobalt(I) complexes derived from dicarbonyltricyanocobaltate(I) [PDF]
, 1971 The preparation and characterization of several series of mixed ligand cobalt(I) complexes of the types [Co(CN)_2(CO)_2(PR_3)]–, [Co(CN)_2(CO)(PR_3)_2]–, and [Co(CN)(CO)_2(PR_3)_2], prepared by the reactions of tertiary phosphines (PR_3) with [Co(CN)_3 ...
Bercaw, John +2 more
core +1 more source
Phosphine Functionalization of GaAs(111)A Surfaces [PDF]
, 2008 Phosphorus-functionalized GaAs surfaces have been prepared by exposure of Cl-terminated GaAs(111)A surfaces to triethylphosphine (PEt3) or trichlorophosphine (PCl3), or by the direct functionalization of the native-oxide terminated GaAs(111)A surface ...
Biteen, Julie S. +5 more
core +1 more source
Molecules, 2023 Tertiary diethylpyridylphosphine was synthesized by the reaction of pyridylphosphine with bromoethane in a suberbasic medium. The reaction of phosphine with the copper(I) iodide led to the formation of a copper(I) coordination polymer, which, according ...
Kamila R. Enikeeva +11 more
doaj +1 more source
Crystal structure of {[1′-(diphenylphosphino)ferrocenyl]methyl}dimethylammonium chloride monohydrate
Acta Crystallographica Section E: Crystallographic Communications, 2017 Individual ions and the solvating water molecule constituting the structure of the title compound, [Fe(C8H13N)(C17H14P)]Cl·H2O, assemble into dimeric units located around crystallographic inversion centers via N—H...Cl and O—H...Cl hydrogen bonds.
Martin Zábranský, Petr Štěpnička
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Molecules, 2021 A series of emissive Cu(I) cationic complexes with 3-(2-pyridyl)-5-phenyl-pyrazole and various phosphines: dppbz (1), Xantphos (2), DPEPhos (3), PPh3 (4), and BINAP (5) were designed and characterized.
Kristina F. Baranova +5 more
doaj +1 more source
Stoichiometric and Catalytic Synthesis of Alkynylphosphines
Molecules, 2012 Alkynylphosphines or their borane complexes are available either through C–P bond forming reactions or through modification of the phosphorus or the alkynyl function of various alkynyl phosphorus derivatives.
Annie-Claude Gaumont +3 more
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Reactions of HNO with Metal Porphyrins: Underscoring the Biological Relevance of HNO [PDF]
, 2014 Azanone (1 HNO, nitroxyl) shows interesting yet poorly understood chemical and biological effects. HNO has some overlapping properties with nitric oxide (NO), sharing its biological reactivity toward heme proteins, thiols, and oxygen.
Bikiel, Damian Ezequiel +4 more
core +1 more source
Architecture and synthesis of P,N-heterocyclic phosphine ligands
Beilstein Journal of Organic Chemistry, 2020 Diverse P,N-phosphine ligands reported to date have performed exceptionally well as auxiliary ligands in organometallic catalysis. Phosphines bearing 2-pyridyl moieties prominently feature in literature as compared to phosphines with five-membered N ...
Wisdom A. Munzeiwa +2 more
doaj +1 more source
Expanding the scope of ligand substitution from [M(S2C2Ph2] (M = Ni2+, Pd2+, Pt2+) to afford new heteroleptic dithiolene complexes [PDF]
, 2017 The scope of direct substitution of the dithiolene ligand from [M(S2C2Ph2)2] [M = Ni2+ (1), Pd2+ (2), Pt2+ (3)] to produce heteroleptic species [M(S2C2Ph2)2Ln] (n = 1, 2) has been broadened to include isonitriles and dithiooxamides in addition to ...
Donahue, James P. +8 more
core +1 more source
A SF5 Derivative of Triphenylphosphine as an Electron-Poor Ligand Precursor for Rh and Ir Complexes
Molecules, 2020 The synthesis of the triarylphosphine, P(p-C6H4SF5)3 containing a SF5 group, has been achieved. The experimental and theoretical studies showed that P(p-C6H4SF5)3 is a weaker σ-donor when compared with other substituted triarylphosphines, which is ...
Maria Talavera +4 more
doaj +1 more source