Results 11 to 20 of about 14,880 (275)
Activation of Cyanate Anions by Phosphine Radical Cations Enables Formal Hydrocarbamoylation of Alkenes. [PDF]
Angew Chem Int Ed EnglA photocatalytic formal hydrocarbamoylation reaction that employs a cyanate anion as the C1 source and provides N‐acyl iminophosphorane products from activated alkenes is described. Mechanistic investigations suggest generation of a phosphoranyl radical by addition of the cyanate anion to a phosphine radical cation, which enables the delivery of the ...
Vojáčková P, Studer A.
europepmc +3 more sources
Asymmetric Synthesis of Contact Sex Pheromone of Tetropium fuscum and Its Enantiomer
Molecules, 2022 Tetropium fuscum is a harmful forest pest and attacks spruces. The contact sex pheromone of this pest, (S)-11-methyl-heptacosane, and its enantiomer were synthesized via Evans’ chiral auxiliaries.
Xueyang Wang +5 more
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Green Energy & Environment, 2019 Despite the similarity of ionic liquid and zwitterion, their some properties such as conductivity and hydrophobicity are different. Here we developed a novel phosphonium salt having a dynamic covalent bond between anion and cation, enabling reversible ...
Kosuke Kuroda +2 more
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Rasta resin-PPh3BnCl and its use in chromatography-free carbonyl cyanosilylation reactions [PDF]
, 2011 Rasta resin-PPhnCl, a new heterogeneous polystyrene-based phosphonium salt, has been synthesized and used to catalyze cyanosilylation reactions of aldehydes and ketones.
Teng, Y, Toy, PH
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Zaporožskij Medicinskij Žurnal, 2017 Uncontrolled use of antimicrobial drugs leads to the selection and spread of resistant strains of microorganisms. Рhosphonium compounds and their derivatives have been chosen as very perspective during searching of new highly active antimicrobial and ...
A. V. Gumenna +4 more
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Journal of Fundamental and Applied Sciences, 2018 The present work is aimed mainly to synthesize a phosphonuim salt, methyl triphenylphosphonuim iodide, and evaluate inhibitive effect against carbon steel corrosion in aerated 1 M HCl solutions.
H. Zerrouki +3 more
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, 2020 A new stable phosphorus ylide (p-tolyl)(3)P = CHCOC6H4(p-CN) (Y) was synthesized and a series of novel complexes based on metalated phosphorus ylides were prepared through the reaction of (p-tolyl)(3)P = CHCOC6H4(p-CN) with mercury(II) halides, AgNO3 and
Bayat, Mehdi +5 more
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Transport of Zn(II), Fe(II), Fe(III) across polymer inclusion membranes (PIM) and flat sheet supported liquid membranes (SLM) containing phosphonium ionic liquids as metal ion carriers [PDF]
, 2016 This is an Accepted Manuscript of an article published by Taylor & Francis Group in Separation Science and Technology on 18/04/2016, available online: http://www.tandfonline.com/doi/full/10.1080/01496395.2016.1174265In this work transport of Zn(II), Fe ...
Baczynska, Monika +5 more
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Acta Crystallographica Section E: Crystallographic Communications, 2016 The title hydrated salt, C26H32O3P+·Cl−·H2O, contains four different substituents (H, alkyl, aryl, and biaryl) on the P atom. The P—H hydrogen atom of the phosphonium ion was located in a difference Fourier map and refined without imposing additional ...
Ge Feng +2 more
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Spontaneous dehydrocoupling in peri-substituted phosphine-borane adducts [PDF]
, 2016 This work was financially supported by the EPSRC and COST action CM1302 SIPs.Bis(borane) adducts Acenap(PiPr2·BH3)(PRH·BH3) (Acenap = acenaphthene-5,6-diyl; 4a, R = Ph; 4b, R = ferrocenyl, Fc; 4c, R = H) were synthesised by the reaction of excess H3B ...
Cordes, David Bradford +6 more
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