Results 21 to 30 of about 14,880 (275)

Extraction of Wheat Straw with Aqueous Tetra-n-Butylphosphonium Hydroxide

open access: yesBioResources, 2014
The stability of tetra-n-butylphosphonium hydroxide ([P4444][OH](aq)) solutions and their potential for wheat straw extraction are investigated. Under certain concentration ranges, aqueous [P4444][OH](aq) is known to rapidly dissolve up to 20 wt% of ...
Uula Hyväkkö   +2 more
doaj   +1 more source

Triphenylarsonium-functionalised gold nanoparticles: potential nanocarriers for intracellular therapeutics. [PDF]

open access: yes, 2015
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Two new triphenylarsonium alkylthiolate precursors, a thiosulfate zwitterion and a thioacetate salt, have been structurally characterised and their cytotoxicity evaluated ...
Ahn   +39 more
core   +2 more sources

Comprehensive Review on Synthesis, Properties, and Applications of Phosphorus (PIII, PIV, PV) Substituted Acenes with More Than Two Fused Benzene Rings

open access: yesMolecules, 2022
This comprehensive review, covering the years 1968–2022, is not only a retrospective investigation of a certain group of linearly fused aromatics, called acenes, but also a presentation of the current state of the knowledge on the synthesis, reactions ...
Marek Koprowski   +6 more
doaj   +1 more source

Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation [PDF]

open access: yes, 2016
We report a synthesis method for the construction of quaternary aryl phoshonium salts at ambient temperature. The regiospecific reaction invovles the coupling of phosphines with aryl radicals derived from diaryliodonium salts under photoredox ...
A. F. Fearnley   +66 more
core   +2 more sources

Synthesis and Crystal Structures of New 5,5'-Azotetrazolates

open access: yesCrystals, 2012
Five new 5,5'-azotetrazolate salts (amminsilver, trimethylsulfonium, tetramethyl-phosphonium, trimethylsulfoxonium, 2-(hydroxyethyl)trimethylammonium) were prepared and characterized.
Gerhard Laus   +6 more
doaj   +1 more source

Mechanochemical P-derivatization of 1,3,5-Triaza-7-Phosphaadamantane (PTA) and Silver-Based Coordination Polymers Obtained from the Resulting Phosphabetaines

open access: yesMolecules, 2020
We have described earlier that in aqueous solutions, the reaction of 1,3,5-triaza-7-phosphaadamantane (PTA) with maleic acid yielded a phosphonium-alkanoate zwitterion.
Antal Udvardy   +6 more
doaj   +1 more source

Aminophosphines : a double role in the synthesis of colloidal indium phosphide quantum dots [PDF]

open access: yes, 2016
Aminophosphines have recently emerged as economical, easy-to-implement precursors for making InP nanocrystals, which stand out as alternative Cd-free quantum dots for optoelectronic applications.
De Nolf, Kim   +5 more
core   +1 more source

The use of the reference electrode equipped with an ionic liquid salt bridge in electrochemistry of ionic liquids: A convenient way to align the formal potentials of redox reactions in ionic liquids based on the standard hydrogen electrode scale

open access: yesElectrochemistry Communications, 2021
A hydrophobic ionic liquid composed of a cationic and anionic species having similar magnitudes of hydrophobicity and mobilities can work as a salt bridge separating two electrolyte solutions, that is, the sample solution and the inner solution of the ...
Takashi Kakiuchi   +4 more
doaj   +1 more source

Total Synthesis of (+)‐Melonine and (+)‐N4‐Oxy Melonine Enabled by an Intramolecular Alkene Diamination Reaction

open access: yesAngewandte Chemie, EarlyView.
A complexity‐generating intramolecular alkene diamination constitutes the pivotal step in the enantioselective synthesis of the title natural products featuring a strained, cage‐like pentacyclic architecture. Abstract Among more than four thousand monoterpene indole alkaloids (MIAs) isolated to date, only a few feature a 2,2,3‐trisubstituted indoline ...
Vincent Goëlo, Qian Wang, Jieping Zhu
wiley   +2 more sources

An Improved and Practical Method for Synthesizing of α-Sanshools and Spilanthol

open access: yesFrontiers in Chemistry, 2020
An efficient and practical route for the synthesis of α-sanshools and spilanthol is described herein. Several modifications of an existing method enabled the preparation of the (2E,6Z,8E,10E)-tetraene precursor of hydroxy-α-sanshool in good yield.
Akira Nakamura   +3 more
doaj   +1 more source

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