Radical-Mediated Anti-Markovnikov Hydrophosphonation of Olefins [PDF]
The radical-mediated addition of triphenylphosphonium tetrafluoroborate to olefins (hydrophosphonation) is reported. Both standard radical initiators and photochemical conditions are effective, up to the gram scale.
Daeffler, Christopher S. +1 more
core +1 more source
Abstract Olefin extractive separation from fluid catalytic cracking (FCC) naphtha with deep eutectic solvents (DESs) was systematically investigated in this work. In a first step, different DESs were screened for their separation performance of the binary mixture benzene/1‐hexene.
Gangqiang Yu +6 more
wiley +1 more source
The α-amidoalkylating properties of 1-(N-acylamino)alkyltriarylphosphonium salts with weakened Cα-P+ bond strength are discussed and examined.
Jakub Adamek +4 more
doaj +1 more source
From Broad-Spectrum Biocides to Quorum Sensing Disruptors and Mussel Repellents: Antifouling Profile of Alkyl Triphenylphosphonium Salts [PDF]
30 páginas, 13 figuras, 4 tablas.-- This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and
Babarro, José M. F. +6 more
core +3 more sources
Towards Axially Chiral Pyrazole‐Based Phosphorus Scaffolds by Dipeptide‐Phosphonium Salt Catalysis [PDF]
Jia‐Hong Wu +6 more
openalex +1 more source
Ab Initio Molecular Dynamics Study of Quadrupolar Spin Relaxation in an Ionic Liquid
This study presents a methodology for describing the relaxation of nuclear spins (with I > 1/2), applicable to ionic liquids of a general nature. Based on ab initio molecular dynamics, we demonstrate the importance of explicit solvation in calculating the relaxation times of the quadrupolar mechanism.
Luciano N. Vidal +2 more
wiley +1 more source
Asymmetric Mannich/Radical Debromination Cascade of α‐Bromoketones by Dipeptide‐Phosphonium Salt Catalysis: Enantioselective Synthesis of β‐Amino Ketone‐Pyrazolinones [PDF]
Jixing Che +5 more
openalex +1 more source
Synthesis of the Sex Pheromones of the Pine Caterpillar, Dendrolimus punctatus (Walker)
The pine caterpillar, Dendrolimus punctatus (Walker), is a notorious forest pest. An efficient and convenient synthesis of the sex pheromones of this pest has been achieved.
Chuanwen Lin +4 more
doaj +1 more source
Tetrakis(benzylamino)phosphonium chloride
The title salt, [P(NHCH2C6H5)4]+·Cl−, crystallizes with the P atom and Cl− anion lying on a twofold rotation axis. The P atom has a slightly distorted tetrahedral geometry with two classes of N—P—N angles [
Khodayar Gholivand +2 more
doaj +1 more source
Silicon containing electroconductive polymers and structures made therefrom [PDF]
An electropolymerized film comprised of polymers and copolymers of a monomer is formed on the surface of an anode. The finished structures have superior electrical and mechanical properties for use in applications such as electrostatic dissipation and ...
Distefano, Salvador +2 more
core +1 more source

