Results 11 to 20 of about 4,438 (202)

Modeling and Simulation of Reaction Environment in Photoredox Catalysis: A Critical Review

open access: yesFrontiers in Chemical Engineering, 2022
From the pharmaceutical industry’s point of view, photoredox catalysis has emerged as a powerful tool in the field of the synthesis of added-value compounds.
Gabriela Xavier de Oliveira   +4 more
doaj   +1 more source

Photoredox Catalysis Using Heterogenized Iridium Complexes** [PDF]

open access: yesChemistry – A European Journal, 2021
Abstract Heterogenized photoredox catalysts provide a path for sustainable chemical synthesis using highly tunable, reusable constructs. Here, heterogenized iridium complexes as photoredox catalysts were assembled via covalent attachment to metal oxide surfaces (ITO, ZrO 2 ,
Kelly L. Materna, Leif Hammarström
openaire   +3 more sources

Asymmetric counteranion-directed photoredox catalysis

open access: yesScience, 2023
Photoredox catalysis enables distinctive and broadly applicable chemical reactions, but controlling their selectivity has proven to be difficult. The pursuit of enantioselectivity is a particularly daunting challenge, arguably because of the high energy of the activated radical (ion) intermediates, and previous approaches have invariably required ...
Sayantani Das   +5 more
openaire   +5 more sources

Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations

open access: yesNature Communications, 2021
The generation of alkyl radicals through deoxygenation of abundant alcohols via photoredox catalysis is of interest. In this study, the authors report a one-pot strategy for visible-light-promoted photoredox coupling of alcohols with electron-deficient ...
Hong-Mei Guo, Xuesong Wu
doaj   +1 more source

Recent Synthetic Applications of the Hypervalent Iodine(III) Reagents in Visible-Light-Induced Photoredox Catalysis

open access: yesFrontiers in Chemistry, 2020
The synergistic combination of visible-light-induced photoredox catalysis with hypervalent iodine(III) reagents (HIRs) represents a particularly important achievement in the field of hypervalent iodine chemistry, and numerous notable organic ...
Chaoyue Chen   +3 more
doaj   +1 more source

Recent Advances in Visible-Light Photoredox Catalysis for the Thiol-Ene/Yne Reactions

open access: yesMolecules, 2022
Visible-light photoredox catalysis has been established as a popular and powerful tool for organic transformations owing to its inherent characterization of environmental friendliness and sustainability in the past decades.
Qian Xiao, Qing-Xiao Tong, Jian-Ji Zhong
doaj   +1 more source

Ketones from aldehydes via alkyl C(sp3)−H functionalization under photoredox cooperative NHC/palladium catalysis

open access: yesNature Communications, 2023
Direct synthesis of ketones from aldehydes features high atom- and step-economy. Yet, the coupling of aldehydes with unactivated alkyl C(sp3)-H remains challenging.
Hai-Ying Wang   +4 more
doaj   +1 more source

Combined Photoredox Catalysis for Value-Added Conversion of Contaminants at Spatially Separated Dual Active Sites

open access: yesResearch, 2023
As 2 indispensable counterparts in one catalysis system, the independent reduction and oxidation reactions require synergetic regulation for cooperatively promoting redox efficiency.
Jieyuan Li   +8 more
doaj   +1 more source

Oxidase reactions in photoredox catalysis

open access: yesChemical Society Reviews, 2021
This tutorial review highlights the distinctive mechanistic roles of and practical considerations regarding terminal oxidants in photocatalytic “oxidase”-type reactions.
Nicholas L. Reed, Tehshik P. Yoon
openaire   +3 more sources

RECENTES APLICAÇÕES EM SÍNTESE ORGÂNICA DE CATÁLISE FOTO REDOX MEDIADA POR LUZ VISÍVEL

open access: yesQuímica Nova, 2015
In the past few years, photoredox catalysis has become a powerful tool in the field of organic synthesis. Using this efficient method, it is possible to excite organic compounds from visible light and attain alternative mechanistic pathways for the ...
Angelina M. de Almeida   +2 more
doaj   +1 more source

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