Results 11 to 20 of about 4,438 (202)
Modeling and Simulation of Reaction Environment in Photoredox Catalysis: A Critical Review
From the pharmaceutical industry’s point of view, photoredox catalysis has emerged as a powerful tool in the field of the synthesis of added-value compounds.
Gabriela Xavier de Oliveira +4 more
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Photoredox Catalysis Using Heterogenized Iridium Complexes** [PDF]
Abstract Heterogenized photoredox catalysts provide a path for sustainable chemical synthesis using highly tunable, reusable constructs. Here, heterogenized iridium complexes as photoredox catalysts were assembled via covalent attachment to metal oxide surfaces (ITO, ZrO 2 ,
Kelly L. Materna, Leif Hammarström
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Asymmetric counteranion-directed photoredox catalysis
Photoredox catalysis enables distinctive and broadly applicable chemical reactions, but controlling their selectivity has proven to be difficult. The pursuit of enantioselectivity is a particularly daunting challenge, arguably because of the high energy of the activated radical (ion) intermediates, and previous approaches have invariably required ...
Sayantani Das +5 more
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Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
The generation of alkyl radicals through deoxygenation of abundant alcohols via photoredox catalysis is of interest. In this study, the authors report a one-pot strategy for visible-light-promoted photoredox coupling of alcohols with electron-deficient ...
Hong-Mei Guo, Xuesong Wu
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The synergistic combination of visible-light-induced photoredox catalysis with hypervalent iodine(III) reagents (HIRs) represents a particularly important achievement in the field of hypervalent iodine chemistry, and numerous notable organic ...
Chaoyue Chen +3 more
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Recent Advances in Visible-Light Photoredox Catalysis for the Thiol-Ene/Yne Reactions
Visible-light photoredox catalysis has been established as a popular and powerful tool for organic transformations owing to its inherent characterization of environmental friendliness and sustainability in the past decades.
Qian Xiao, Qing-Xiao Tong, Jian-Ji Zhong
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Direct synthesis of ketones from aldehydes features high atom- and step-economy. Yet, the coupling of aldehydes with unactivated alkyl C(sp3)-H remains challenging.
Hai-Ying Wang +4 more
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As 2 indispensable counterparts in one catalysis system, the independent reduction and oxidation reactions require synergetic regulation for cooperatively promoting redox efficiency.
Jieyuan Li +8 more
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Oxidase reactions in photoredox catalysis
This tutorial review highlights the distinctive mechanistic roles of and practical considerations regarding terminal oxidants in photocatalytic “oxidase”-type reactions.
Nicholas L. Reed, Tehshik P. Yoon
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RECENTES APLICAÇÕES EM SÍNTESE ORGÂNICA DE CATÁLISE FOTO REDOX MEDIADA POR LUZ VISÍVEL
In the past few years, photoredox catalysis has become a powerful tool in the field of organic synthesis. Using this efficient method, it is possible to excite organic compounds from visible light and attain alternative mechanistic pathways for the ...
Angelina M. de Almeida +2 more
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