Results 131 to 140 of about 3,943 (245)
Switchable molecular tweezers: design and applications
Switchable molecular tweezers are a unique class of molecular switches that, like their macroscopic analogs, exhibit mechanical motion between an open and closed conformation in response to stimuli.
Pablo Msellem +3 more
doaj +1 more source
The Radical Chemistry of 2,3‐Diguanidinopyridines: Coordination and Visible‐Light Photochemistry
Substitution at the pyridine core of 2,3‐diguanidinopyridines was used to develop novel redox‐active molecules with three interconvertible redox states. They are applied as redox‐active ligands in coordination chemistry. Visible‐light irradiation of the pyridine N‐benzylated molecules leads to photoconversion to a higher‐energetic isomer.
Hanna Koepcke +3 more
wiley +1 more source
Understanding X-ray-induced isomerisation in photoswitchable surfactant assemblies
Dynamic, responsive materials can be built using photosurfactants (PS) that self-assemble into ordered nanostructures, such as micelles or liquid crystals.
Beatrice E. Jones +5 more
doaj +1 more source
Unipolar Barrier Near‐Infrared 2D Photodetectors for 3D Image Sensors
A MoTe2/WSe2/Cl–SnSe2 unipolar barrier photodetector is demonstrated, in which the WSe2 layer effectively blocks majority‐carrier injection, yielding suppressed dark current and enhanced near‐infrared (NIR) sensing. The device achieves high detectivity, a wide linear dynamic range, and fast response under 1310 nm illumination, enabling high‐fidelity 3D
Jung Pyo Hong +21 more
wiley +1 more source
On the Molecular Origin of Photoinduced Dimerization of 3‐ and 4‐Phenylcoumarin
Two isomers with different photochemistry: Transient absorption spectroscopy and TD‐DFT show that 3‐phenyl‐7‐methoxycoumarin reaches a long‐lived triplet state after planarization of its phenyl ring and dimerizes, whereas 4‐phenyl‐7‐methoxycoumarin returns to the ground state within picoseconds along the lactone C–O coordinate.
Pavel V. Kolesnichenko +6 more
wiley +1 more source
Machine Learning–Enhanced Fluorescence Cryptography with NADH‐Responsive Polymer Dots
This study presents a smart anticounterfeiting system using semiconducting polymer dots (Pdots) that exhibit tunable fluorescence responses to NADH. By integrating these dynamic optical signals with machine learning–based decoding, the work establishes a secure and intelligent encryption platform, showing a novel strategy that links chemical sensing ...
Zhengkun Zhan +7 more
wiley +1 more source
Mechanical Caging of Nucleic Acids Enabled by Light‐Activated Synthetic Molecular Motors
A synthetic light‐driven molecular motor imposes mechanical constraints on nucleic acids, enabling “mechanical caging” as a new mode to regulate DNA structure and function through mechanical input rather than chemical masking. ABSTRACT Control over nucleic acid activity is central to biotechnology and therapeutic development.
Yuchen Ma +10 more
wiley +2 more sources
Hydrazopyridinium lead iodide combines near‐linear Pb─I─Pb bonding with a 2.13 eV bandgap in a two‐dimensional Dion–Jacobson perovskite. Spacer‐controlled crystal engineering enables broadband UV‐to‐visible photodetection with enhanced deep‐UV sensitivity.
Avija Ajayakumar +9 more
wiley +1 more source
Rapid Access to Photoswitchable RNA Binders: Fluorination Enhances Protein Rescue by Exon Inclusion
An adaptable approach, many light‐switchable RNA binders. We report a versatile strategy for rapidly synthesizing photoswitchable RNA binders. The ligands can target SMN2 pre‐mRNA, restoring the levels of the corresponding protein by exon‐inclusion rescue.
Lei Zhang +10 more
wiley +1 more source
Multi‐state Photoswitching in Thienoquinoid‐Based Fluorescent Trithiophenes
A methine‐bridged trithiophene with a thienoquinoid core undergoes photoisomerization of both C═C bonds, affording three geometrical isomers in a ratio controlled by the irradiation wavelength. Despite full π‐conjugation, the system retains fluorescence, enabling wavelength‐addressable multi‐state switching with luminescent readout.
Rio Nishimura +3 more
wiley +1 more source

