Results 151 to 160 of about 1,474,092 (264)

Synthesis of a π‐Extended Phenazine Diimide Derivative and Characterization of Its Closed‐Shell Reduced States

Chemistry – A European Journal, EarlyView.
In this work, the synthesis and characterization of novel π‐extended phenazine diimides is reported. The derivatives undergo differential reduction to a dihydrophenazine or Meisenheimer form depending on the reaction conditions employed. The outcome of this work highlights the paramount importance of structural design in determining the nature of the ...
Francesco Rigodanza, Beatrice Bartolomei, Ilaria Crea, Paolo Costa, Nicola Demitri, Marcella Bonchio, Maurizio Prato, Jacopo Dosso   +7 more
wiley   +1 more source

Photoelectrochemical Hydrogen Peroxide Production via Simultaneous Reduction and Oxidation Processes

Chemistry – A European Journal, EarlyView.
Hydrogen peroxide (H2O2) is an important chemical substance and also a promising carbon‐free clean fuel. The design of a sophisticated photoelectrochemical (PEC) reaction system enables the solar‐driven H2O2 production through simultaneous water oxidation and oxygen reduction processes (H2O2/H2O2‐PEC cells).
Tetsuro Soejima, Shin‐ichi Naya, Hiroaki Tada   +2 more
wiley   +1 more source

Mimicking The Photosynthetic Special Pair With Aluminum(III) Porphyrin Homodimer – Fullerene (C60) Supramolecular Assemblies Capable of Long‐Lived Charge Separation

Chemistry – A European Journal, EarlyView.
The axial‐bonding of aluminum(III) porphyrins was used to create two covalently linked special‐pair mimics to probe charge‐transfer between a porphyrin dimer and a C60 unit for artificial photosynthesis. Although excitonic coupling between the porphyrins is weak, incorporation of a second porphyrin markedly increases both the yield and lifetime of the ...
Stefan Charon, Jatan K. Sharma, Niloofar Zarrabi, Peyton Ellis, Paul A. Karr, Art van der Est, Francis D'Souza, Prashanth K. Poddutoori   +7 more
wiley   +1 more source

Natural South African iron‐rich sand as a functional catalyst in hybrid photocatalytic wet peroxide oxidation technology for the degradation of methyl orange dye pollutant

The Canadian Journal of Chemical Engineering, EarlyView.
This research explored South African iron‐rich sand (SAIRS) as a natural catalyst for light‐mediated wet peroxide oxidation of methyl orange dye in wastewater and at an optimized of conditions of 3500 mg/L catalyst dose, 6 mM H2O2, and pH 2.5, SAIRS achieved 94% methyl orange degradation within 90 min under visible light.
Aaliyah Ebrahim, Stephen Sunday Emmanuel, Alicia Levana Dorling, Shepherd M. Tichapondwa   +3 more
wiley   +1 more source

Photocatalytic Oxygen Evolution with Prussian Blue Coated ZnO Origami Core‐Shell Nanostructures

ChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Prussian Blue and its derivative hold significant potential for photocatalytic oxygen evolution. IN this contribution the photocatalytic oxygen evolution reaction (OER) was characterized using a hybrid catalyst consisting of Prussian Blue coated ZnO nanostructures. The resulting heterojunction, which was characterized both structurally and functionally,
Ruby Phul, Guobin Jia, Emir Utku Sekercileroglu, Yves Carstensen, Ratnadip De, Andrea Dellith, Jan Dellith, Jonathan Plentz, Ferdi Karadaş, Benjamin Dietzek‐Ivanšić   +9 more
wiley   +1 more source

High atmospheric pressure rescues plant growth under humidity stress: A model for climate‐resilient deep underground agriculture

Deep Underground Science and Engineering, EarlyView.
High atmospheric pressure (120 kPa) in deep underground counteracts humidity‐induced physiological stress in plants, stabilizing water balance and enhancing antioxidative defenses. This synergy boosts biomass despite elevated humidity, demonstrating sustainable deep underground agriculture potential under climate uncertainty.
Yuxin He, Linglu Xu, Xiao Tan, Wenhua Zhuang, Naiwen Li, Chao Liu, Bo Tan   +6 more
wiley   +1 more source

Boosting Water Vapor‐Assisted Methane Photooxidation Over S‐Scheme MIL‐125‐NH2(Ti)/WO3 Heterojunction Photocatalysts

EcoEnergy, EarlyView.
The MIL‐125‐NH2(Ti)/WO3‐x S‐scheme heterostructure was constructed via electrostatic self‐assembly, strategically aligning energy bands to optimize interfacial charge transfer and ·OH generation for C–H activation. The optimized MW‐3 demonstrates exceptional CH4 photooxidation activity using water vapor as a sustainable oxidant, achieving a remarkable ...
Jia‐Min Cao, Jing Ren, Ya‐Ting Zheng, Ya‐Nan Wang, Ye Wang, Wen‐Wen Dong, Jun Zhao, Dong‐Sheng Li, Zhi‐Ming Zhang   +8 more
wiley   +1 more source

Boosting Charge Separation in a CdIn2S4/Mo2TiC2 MXene Schottky Heterojunction for Enhanced Photocatalytic Hydrogen Production

EcoEnergy, EarlyView.
ABSTRACT Mo2TiC2 MXene was exfoliated in situ using hydrofluoric acid solution and subsequently integrated with CdIn2S4 through physical stirring and grinding. The composite material demonstrated exceptional photocatalytic hydrogen evolution (PHE) activity without the loading of any noble metal co‐catalysts, achieving a hydrogen production rate as high
Bingzhu Li, Teng Li, Xiaohua Ma, Minjun Lei, Zhiliang Jin, Noritatsu Tsubaki, Paolo Fornasiero   +6 more
wiley   +1 more source

‘MultiTraits': an integrated R package for analysis and visualization of multidimensional plant traits

Ecography, EarlyView.
The multidimensional characteristics of plant traits and their trade‐offs are central to ecology. However, there is a lack of systematic and standardized tools for analyzing these intricate relationships. To fill this gap, we developed the ‘MultiTraits' R package, which incorporates four complementary analytical modules: competitors–stress tolerators ...
Yan He, Zhaogang Liu, Jiangshan Lai, Lingfeng Mao   +3 more
wiley   +1 more source

Environmental heterogeneity and spatial variation mediates plant diversity and ecosystem stability in mountain ecosystems of the Mediterranean Andes

Ecography, EarlyView.
Globally, mountains are highly diverse ecosystems that serve as natural laboratories for testing ecological theories, while providing vital ecosystem services. Their biodiversity arises from the interaction between elevational gradients and topographic complexity, which generate strong variation in environmental conditions across short spatial scales ...
Laura C. Pérez‐Giraldo, José M. Cerda‐ Paredes, Dylan Craven, Javier Lopatin   +3 more
wiley   +1 more source