Caloric restriction reveals a metabolomic and lipidomic signature in liver of male mice [PDF]
Lipid composition, particularly membrane unsaturation, has been proposed as being a lifespan determinant, but it is currently unknown whether caloric restriction (CR), an accepted life-extending intervention, affects cellular lipid profiles.
Jové, Mariona+6 more
core +3 more sources
Antibiotic‐induced dysbiosis of the gut microbiota shifts host tryptophan metabolism and impairs the innate immune response during Pseudomonas aeruginosa pulmonary infection. (A) Eubiosis: During eubiosis, the intestinal microbiota metabolises tryptophan into indole metabolites, which keeps tryptophan levels within normal serum concentrations. However,
Camila Bernardo de Brito+19 more
wiley +1 more source
Diaquabis(picolinato N-oxide-κ2O,O′)zinc(II)
In the title compound, [Zn(C6H4NO3)2(H2O)2], the Zn atom is located on a centre of inversion and shows a distorted octahedral coordination geometry. Two aqua ligands occupy the axial positions and four O atoms of the two chelating picolinic acid N-oxide ...
Xiu-Bing Li+2 more
doaj +1 more source
Comparison of the Plasma Metabolome Profiles Between the Internal Thoracic Artery and Ascending Aorta in Patients Undergoing Coronary Artery Bypass Graft Surgery Using Gas Chromatography Time-of-Flight Mass Spectrometry. [PDF]
BackgroundThe left internal thoracic artery (LITA) has been used as the first conduit of choice in coronary artery bypass grafting (CABG) because of excellent long-term patency and outcomes.
Cho, Joo Youn+6 more
core
ABSTRACT Rationale Several phytosterols (PSs), well known for their role in plant physiology and their health benefits, represent a subset of the family of 4‐desmethyl‐sterols. They exhibit remarkable structural variability due to differences in the number and position of C=C bonds in their tetracyclic backbone and side chain composition. When analysed
V. Cinquepalmi+4 more
wiley +1 more source
Recent Advances in Homogeneous Metal-Catalyzed Aerobic C–H Oxidation of Benzylic Compounds [PDF]
Csp(3)-H oxidation of benzylic methylene compounds is an established strategy for the synthesis of aromatic ketones, esters, and amides. The need for more sustainable oxidizers has encouraged researchers to explore the use of molecular oxygen.
Domínguez Pérez, Pilar Esther+3 more
core +2 more sources
Mn (II) complex with 4‐iodo‐pyridine‐2‐carboxylic acid and 5,5′‐dimethyl‐2,2′‐bipyridine has shown significant potential for nonlinear optical (NLO) applications, as evidenced by both static and frequency‐dependent NLO analyses. This is attributed to the interaction between Mn (II) ion and the coordinated ligands, which facilitates intramolecular ...
Ömer Tamer+5 more
wiley +1 more source
The limitation for popular descriptions of alpha-relaxation temperature dependence [PDF]
Applicability of three popular functions (Vogel-Fulcher-Tammann, double activation law and frustration-limited domains model) for the description of the temperature dependence of alpha-relaxation time tau_alpha is considered for three typical glass-formers (propylene carbonate, ethanol and picoline). Two first functions have three free parameters.
arxiv
Geometric-algebraic approach to aqueous solutions of diprotic acids and its buffer mixtures [PDF]
A closed-form analytical expression for $\ce{[H3O+]}$ has been obtained for aqueous solutions of diprotic acids and its soluble salts. This formula allows to calculate the pH of aqueous solutions of diprotic acids, their buffer solutions, and the titrations of these two by a strong base, from the values of p$K_1$, p$K_2$, and the effective ...
arxiv
The Crystal Structures of Two Novel Cadmium-Picolinic Acid Complexes in Relation to the Solution Species [PDF]
The crystal structures of two novel cadmium-picolinic acid complexes grown in aqueous solutions at selected pH values are reported. The structures are compared to expected solution species under the same conditions.
Billing, C, Levendis, DC, Vieira, VL
core +1 more source