A new one-pot synthesis of quinoline-2-carboxylates under heterogeneous conditions [PDF]
Quinoline-2-carboxylates are an important subclass of quinoline derivatives largely present in a variety of biologically active molecules, as well as useful ligands in metal-catalyzed reactions.
Ballini, Roberto +4 more
core +5 more sources
Affix polyfunctionality in French deverbal nominalizations
AbstractThis article investigates the semantic polyfunctionality of affixes, i.e. their ability to serve a variety of distinct semantic functions. Based on the analysis of a sample of 3,091 deverbal nouns ending with 46 different suffixes in French, the study examines the diversity of semantic functions realized by deverbal suffixes, the distribution ...
Justine Salvadori, Richard Huyghe
openaire +2 more sources
Correlations between experimental and theoretical adiabatic ionization energies for organic compounds and rate constants for atmospheric reactions with hydroxyl radicals [PDF]
Adiabatic ionization energy (AIE) calculations were performed at the AM1, PM3, PM6, PDDG, HF/QZVP, and B3LYP/QZVP levels of theory on 722 atmospherically relevant organic compounds with available experimental rate constants for atmospheric reactions with
Kaya Forest, Sierra Rayne
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Sequential reactions of aminoalkynes represent a powerful tool to easily assembly biologically important polyfunctionalized nitrogen heterocyclic scaffolds.
Antonio Arcadi +2 more
doaj +1 more source
Coordination chemistry of perhalogenated cyclopentadienes and alkynes. 8. Pentakis(dimethylsilyl)cymantrene [PDF]
Starting from [q5-C5Br5]M n(CO),, the first r-complex of a cyclopentadienyl ligand with five silyl substituents, [q 5-C5(SiMe2H)5M] n(CO),, was prepared by a series of halogen-lithium exchange reactions, followed by silylation with SiMe2HCI.
Hofmann, Julian, Sünkel, Karlheinz
core +1 more source
Evaluating Cellular Polyfunctionality with a Novel Polyfunctionality Index
Functional evaluation of naturally occurring or vaccination-induced T cell responses in mice, men and monkeys has in recent years advanced from single-parameter (e.g. IFN-γ-secretion) to much more complex multidimensional measurements. Co-secretion of multiple functional molecules (such as cytokines and chemokines) at the single-cell level is now ...
Larsen, Martin +5 more
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Gold nanoparticles/silver-bipyridine hybrid nanobelts with tuned peroxidase-like activity [PDF]
Gold nanoparticles-decorated silver-bipyridine coordination polymers with intrinsic peroxidase-like activity are reported. Both morphology and mimetic enzyme activity can be tuned by rational manipulation of the nanohybrid composition.
Boujakhrout, Abderrahmane +8 more
core +2 more sources
Highly selective electrochemical hydrogenation of alkynes: Rapid construction of mechanochromic materials [PDF]
Electrochemical hydrogenation has emerged as an environmentally benign and operationally simple alternative to traditional catalytic reduction of organic compounds.
Ge, Haibo, Li, Bijin
core +1 more source
Recent advances in the total synthesis of agelastatins [PDF]
Agelastatins represent an important family of marine alkaloids in terms of both exceptional biological activity and intriguing chemical structure.
Dong, Guangbin
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Diverted domino reactivity in tertiary skipped diynes: A convenient access to polyfunctionalized cyclohexadienones and multivalent aromatic scaffolds [PDF]
Diverting is the game! A new domino manifold has been implemented for the synthesis of cyclohexadienone-based scaffolds from tertiary skipped diynes and secondary amines.
García-Tellado, Fernando +3 more
core +1 more source

