Results 101 to 110 of about 155,987 (342)

Water Soluble Cationic Porphyrin Sensor for Detection of Hg2+, Pb2+, Cd2+, and Cu2+ [PDF]

open access: yes, 2016
Here we report the sensing properties of the aqueous solution of mesotetra(N-methyl-4-pyridyl)porphine tetrachloride (1) for simultaneous detection of toxic metal ions by using UV-vis spectroscopy.
Orr, Christopher   +2 more
core   +4 more sources

Advancing Metal–Organic Framework‐Based Composites for Effective Chemical Warfare Agent Detoxification under Real‐World Conditions

open access: yesAdvanced Materials, EarlyView.
This review describes recent developments in the design and synthesis of metal–organic frameworks (MOF)/textile composites for the detoxification of chemical warfare agent and simulants with extensive discussion on the advantages and disadvantages of different methods.
Zhihua Cheng   +4 more
wiley   +1 more source

Reactions of HNO with Metal Porphyrins: Underscoring the Biological Relevance of HNO [PDF]

open access: yes, 2014
Azanone (1 HNO, nitroxyl) shows interesting yet poorly understood chemical and biological effects. HNO has some overlapping properties with nitric oxide (NO), sharing its biological reactivity toward heme proteins, thiols, and oxygen.
Bikiel, Damian Ezequiel   +4 more
core   +1 more source

Advancements in Understanding the Physicochemical Properties of Reticular Materials: An In Situ and Operando Spectroscopic Perspective

open access: yesAdvanced Materials, EarlyView.
This review explores how in situ and operando spectroscopic techniques reveal the real‐time behavior of reticular materials, including MOFs and COFs. These methods track material formation and functionalization, structural changes, defect formation, dynamic responses to external triggers, and catalytic processes.
Bettina Baumgartner   +4 more
wiley   +1 more source

Amphiphilic Porphyrin Aggregates: A DFT Investigation

open access: yesMolecules, 2019
Owing to the attractive potential applications of porphyrin assemblies in photocatalysis, sensors, and material science, studies presently concerning porphyrin aggregation are widely diffused.
Federica Sabuzi   +4 more
doaj   +1 more source

Solvothermal Template‐Induced Hierarchical Porosity in Covalent Organic Frameworks: A Pathway to Enhanced Diffusivity

open access: yesAdvanced Materials, EarlyView.
Hierarchically porous covalent organic frameworks (hCOFs) are constructed using a solvothermal template‐induced synthetic strategy. Commercially available zinc oxide nanoparticles are employed as hard template enabling an increase in total pore volume in a series of COFs.
Fabian Heck   +6 more
wiley   +1 more source

Electrically addressing the spin of a magnetic porphyrin through covalently connected graphene electrodes [PDF]

open access: yes, 2019
We report on the fabrication and transport characterization of atomically-precise single molecule devices consisting of a magnetic porphyrin covalently wired by graphene nanoribbon electrodes. The tip of a scanning tunneling microscope was utilized to contact the end of a GNR-porphyrin-GNR hybrid system and create a molecular bridge between tip and ...
arxiv   +1 more source

When do tripdoublet states fluoresce? A theoretical study of copper(II) porphyrin [PDF]

open access: yesarXiv, 2023
Open-shell molecules rarely fluoresce, due to their typically faster non-radiative relaxation rates compared to closed-shell ones. Even rarer is the fluorescence from states that have two more unpaired electrons than the open-shell ground state, for example tripdoublet states (a triplet excitation antiferromagnetically coupled to a doublet state).
arxiv  

Responsive Molecules for Organic Neuromorphic Devices: Harnessing Memory Diversification

open access: yesAdvanced Materials, EarlyView.
Responsive molecules are essential for organic in‐sensor computing devices. This Review highlights recent advances in thedesign, synthesis, and incorporation of electrically, optically, and magnetically responsive molecules in multifunctional synaptic perception devices endowedwith both nonvolatile and volatile memory diversification. By exploiting the
Yusheng Chen   +4 more
wiley   +1 more source

Altering the Coordination of Iron Porphyrins by Ionic Liquid Nanodomains in Mixed Solvent Systems [PDF]

open access: yes, 2017
The solvent environment around iron porphyrin complexes was examined using mixed molecular/RTIL (room temperature ionic liquid) solutions. The formation of nanodomains in these solutions provides different solvation environments for substrates that could
Atifi   +56 more
core   +2 more sources

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