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Mechanistic possibilities in prebiotic thiophosphate chemistry

Journal of Molecular Evolution, 1978
Two types of reactivities of thiophosphates have been demonstrated: one being nucleophilic displacement by the P-S moiety of nucleoside phosphorothioates and the other, phosphorylation via P-S cleavage as the driving force. We have designed a system where both displacement on carbon and P-S cleavage are possible.
Joseph Nagyvary, Istvan Kapovits
openaire   +3 more sources

Rooting Prebiotic Chirality in Spinomeric Chemistry?

Astrobiology, 2009
Spinomeric chemistry is a domain of physical chemistry that explores the role of spin-isomery in chemical reactivity. In large magnetic fields (B), chemical structures with three adjacent nuclear spins (such as H(2)(17)O, H(2)(33)S,-NH(2), and and -(13)CH(2)-) form complex spinomers.
Vily Marius Cimpoiaşu   +2 more
openaire   +3 more sources

Life's Biological Chemistry: A Destiny or Destination Starting from Prebiotic Chemistry?

Chemistry, 2018
Research into understanding the origins-and evolution-of life has long been dominated by the concept of taking clues from extant biology and extrapolating its molecules and pathways backwards in time.
R. Krishnamurthy
semanticscholar   +1 more source

Recent progress in the prebiotic chemistry of HCN

Origins of Life, 1984
This article reports some recent results on the mechanisms of synthesis of biologically important molecules in oligomerizing solutions of HCN. It will also attempt to summarize, as completely as possible, our present state of knowledge concerning the range of products obtained under a variety of conditions in this reaction system.
Alan W. Schwartz   +2 more
openaire   +3 more sources

Prebiotic Chemistry of HCN Tetramerization by Automated Reaction Search.

Chemistry, 2018
HCN oligomerization is considered to be one of the important pathways in chemical evolution. Nucleobases, aminoacids, and many other complex organic molecules can evolve through this pathway.
Surajit Nandi   +2 more
semanticscholar   +1 more source

Silica Metal Oxide Vesicles Catalyze Comprehensive Prebiotic Chemistry.

Chemistry, 2018
It has recently been demonstrated that mineral self-assembled structures catalyzing prebiotic chemical reactions may form in natural waters derived from serpentinization, a geological process widespread in the early stages of Earth-like planets.
Bruno Mattia Bizzarri   +5 more
semanticscholar   +1 more source

Formamide-based prebiotic chemistry in the Phlegrean Fields

Advances in Space Research, 2018
Understanding the formation of biogenic molecules in abiotic conditions is a prerequisite in the origin-of-life studies. Determining the conditions allowing an efficient one-pot synthesis of the largest possible panel of biogenic compounds may shed light on the plausible scenario in which the processes that kick-started life might have occurred.
Rosario Avino   +12 more
openaire   +7 more sources

Physical non-equilibria for prebiotic nucleic acid chemistry

Nature Reviews Physics, 2023
A. Ianeselli   +6 more
semanticscholar   +1 more source

The cometary connection with prebiotic chemistry

Origins of Life, 1984
Amino-acids, purines and pyrimidines may have been formed in space and brought down to Earth by comets during the final stage of the Earth's cold accretion from dust. Present-day comets seem to be the remnants of the building blocks of the early solar system, put for 4.6 billion years in “parking orbits” in the deep cold of space by the same process of
openaire   +2 more sources

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