Hemisynthesis and Absolute Configuration of novel 6-pentyl-2H-pyran- 2-one derivatives from Trichoderma spp [PDF]
A comparative study of the secondary metabolism of two Trichoderma spp. with that of the Thctf1 transcription factor gene null mutant of Trichoderma harzianum 34 was carried out in order to deepen our knowledge of the biosynthetic pathway and mode of ...
Benitez +40 more
core +4 more sources
Selective Oxygenation of 3,4-Dihydro-2H-Pyran to 5,6-Dihydro-2H-Pyran-2-One With Pd/C Catalyst and Molecular Oxygen. [PDF]
Selective oxygenation: The oxidation of 3,4‐dihydro‐2H‐pyran, which can be produced from lignocellulose‐derived furfural, was investigated with various catalysts using O2 as an oxidant in a H2O solvent. 5,6‐dihydro‐2H‐pyran‐2‐one, a value‐added product, was obtained in 52% yield with reusable Pd/C catalyst.
Kawabata N +3 more
europepmc +2 more sources
In the title compound, C24H24N2O6, the mean planes of the pyran rings (A and B) are inclined to one another by 69.2 (1)°, while the aromatic ring (D) of the chromene ring system makes dihedral angles of 63.42 (11) and 66.81 (12)° with the pyrimidine (C ...
S. Gomathi +4 more
doaj +1 more source
Novel tetrahydrobenzo[b]thienopyrole derivatives were synthesized from 2-amino-3-cyano-4,5,6,7-tetrahydrobenzo[b]thiophene (1) through its reaction with α-chloroacetone to give the corresponding N-alkyl derivative 3.
Rafat Milad Mohareb +2 more
doaj +1 more source
Extending Human Perception of Electromagnetic Radiation to the UV Region through Biologically Inspired Photochromic Fuzzy Logic (BIPFUL) Systems. [PDF]
Photochromic Fuzzy Logic Systems have been designed that extend human visual perception into the UV region. The systems are founded on a detailed knowledge of the activation wavelengths and quantum yields of a series of thermally reversible photochromic ...
Albus +35 more
core +1 more source
The title compounds, 6-(naphthalen-1-yl)-6a-nitro-6,6a,6 b,7,9,11a-hexahydrospiro[chromeno[3′,4′:3,4]pyrrolo[1,2-c]thiazole-11,11′-indeno[1,2-b]quinoxaline], C37H26N4O3S, (I), and 6′-(naphthalen-1-yl)-6a′-nitro-6′,6a′,6b′,7′,8′,9′,10′,12a′-octahydro-2H ...
G. Foize Ahmad +4 more
doaj +1 more source
Stereoselective protecting group free synthesis of d,l-gulose ethyl glycoside via multicomponent enyne cross metathesis—hetero Diels–Alder reaction [PDF]
An efficient and stereoselective synthesis of d,l-gulose was described. The key step of the synthetic route is represented by a multicomponent enyne cross metathesis—hetero Diels–Alder reaction which allows the formation of the pyran ring from cheap and ...
Aoyagi +22 more
core +1 more source
The synthesis of 4H-pyran containing hemispherands via pyrylium salts [PDF]
Two new hemispherands 2a and 2b containing a central 4H-pyran unit were synthesized via appropiately substituted 2,6-phenyl pyrylium salts; largest ΔGo values of complexation of 2a and 2b with different alkali picrates are found for Na+ and K+
Dijkstra, P.J. +4 more
core +2 more sources
Mechanism and Application of Baker–Venkataraman O→C Acyl Migration Reactions [PDF]
This literature review focuses on the O→C acyl migration of aryl esters to yield the corresponding 1,3-dicarbonyl products—a reaction known as the Baker–Venkataraman rearrangement—and outlines their subsequent transformations.
Ameen, Dana, Snape, Timothy James
core +1 more source
Phenolic Compounds in Bacterial Inactivation: A Perspective from Brazil
Phenolic compounds are natural substances that are produced through the secondary metabolism of plants, fungi, and bacteria, in addition to being produced by chemical synthesis.
Angélica Correa Kauffmann +1 more
doaj +1 more source

