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Thermal rearrangements of 3H-pyrazoles, 4H-pyrazoles, and cyclopentadienes
19923H-Pyrazoles generally undergo thermal rearrangement by concerted [1,5]-sigmatropic migrations. It has been discovered that 3H-pyrazoles 111a-e undergo thermal rearrangement by an alterative mechanism. A stepwise, ion-pair, mechanism operates in these rearrangements, in benzene/toluene, chloroform, and methanol solvents.
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Chloromethylation of pyrazole ring
Russian Journal of General Chemistry, 2015A. A. Saakyan+3 more
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Kinetics and Mechanism of Iodination of Pyrazole. Comparative Reactivities of Pyrazole and Imidazole
Journal of the American Chemical Society, 1964Virginia L. Vaughan+2 more
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