A NiH‐catalyzed α‐alkenylation via Markovnikov hydronickellation of alkynes enables convenient access to α‐chrial β‐methylene carbonyl frameworks that are prevalent in biorelevant molecules. High regio‐ and enantioselectivities have been achieved with excellent functional group tolerance and applicability toward complex structures. The β‐methylene unit
Hyeontaek Nam +3 more
wiley +1 more source
Precise Semi-Experimental Equilibrium (<i>r</i><sub><i>e</i></sub><sup>SE</sup>) Structure of Pyridine from 32 Isotopologues: Accurate Assessment of the Effect of Nitrogen-Atom Substitution in Aromatic Rings. [PDF]
Zdanovskaia MA +7 more
europepmc +1 more source
Exploring the anti-virulent potential of pyridine derivatives against <i>Vibrio cholerae</i>. [PDF]
Sajeevan A +4 more
europepmc +1 more source
In silico evaluation of (benzo)chromeno[3,4-c]pyridine derivative as dual EGFR/HER2 inhibitors for non-small cell lung cancer. [PDF]
Luke U, Emeng IE, Gber NI, Iyam SO.
europepmc +1 more source
Photochemical Rearrangements of Pyridine N-Oxides: Pathways to Oxaziridine Derivatives. [PDF]
Guerra CJ +11 more
europepmc +1 more source
First Total Synthesis of Pestasulfamides A and B Through Iminoketene Dimerization of Anthranilic Acid in One-Pot Manner. [PDF]
Kobori Y, Abe T.
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Metal‐Free Scission of the NO+ Triple Bond
Breaking bonds: The reaction between NO[Al(ORF)4] (RF = C(CF3)3) and the diphosphane PNPtBu (2,6‐bis(di‐tert‐butylphosphino‐methyl)pyridine) leads to the direct and complete cleavage of the NO+ triple bond, one of the strongest chemical bonds known. The mechanism of this reaction was studied using quantum chemical calculations and NMR spectroscopic ...
Julie Willrett +3 more
wiley +1 more source
Multimodal characterization of a pyrazolo[3,4-<i>b</i>]pyridine aldehyde: quantum chemical insights, NLO activity and VEGFR-2 docking/molecular dynamics. [PDF]
Acosta-Quiroga K +8 more
europepmc +1 more source

