Results 31 to 40 of about 340,813 (275)

Galactosylsphingamides : new α-GalCer analogues to probe the F’-pocket of CD1d [PDF]

open access: yes, 2017
Invariant Natural Killer T-cells (iNKT-cells) are an attractive target for immune response modulation, as upon CD1d-mediated stimulation with KRN7000, a synthetic alpha-galactosylceramide, they produce a vast amount of cytokines.
Decruy, Tine   +9 more
core   +1 more source

Synthesis of Phosphorus(V)-Substituted Six-Membered N-Heterocycles: Recent Progress and Challenges

open access: yesMolecules, 2023
Heterocycles functionalized with pentavalent phosphorus are of great importance since they include a great variety of biologically active compounds and pharmaceuticals, advanced materials, and valuable reactive intermediates for organic synthesis ...
Yulia Volkova, Igor Zavarzin
doaj   +1 more source

Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides [PDF]

open access: yes, 2010
The first systematic mechanism study of C−F reductive elimination from a transition metal complex is described. C−F bond formation from three different Pd(IV) fluoride complexes was mechanistically evaluated.
Benitez, Diego   +6 more
core   +2 more sources

Synthetic Approach to Diversified Imidazo[2,1-b][1,3]thiazines and Its Evaluation as Non-Steroidal Anti-Inflammatory Agents

open access: yesChemistry Proceedings, 2021
The present work is devoted to the synthesis of imidazo[2,1-b][1,3]thiazine derivatives as possible anti-inflammatory agents. The synthetic approach to (2-pyridinyloxy) substituted imidazo[2,1-b][1,3]thiazines based on the interaction of the ...
Nataliia Slyvka   +3 more
doaj   +1 more source

Imide and isatin derivatives as β-lactam mimics of β-lactam antibiotics [PDF]

open access: yes, 2002
Activated γ-lactams, which are derivatives of succinimide, phthalimide and isatin with suitable elements of molecular recognition, have been synthesised as mimics of the ß-lactam antibiotics and their chemical and biological reactivity ...
Casey, Lorraine A.   +4 more
core   +1 more source

[2,2′-Bipyridin]-6(1H)-one, a Truly Cooperating Ligand in the Palladium-Mediated C–H Activation Step: Experimental Evidence in the Direct C-3 Arylation of Pyridine [PDF]

open access: yes, 2018
Producción CientíficaThe ligand [2,2′-bipyridin]-6(1H)-one (bipy-6-OH) has a strong accelerating effect on the Pd- catalyzed direct arylation of pyridine or arenes.
Albéniz Jiménez, Ana Carmen   +2 more
core   +4 more sources

5,6-Bis(pyridin-2-yl)-2,3-dihydropyrazine

open access: yesIUCrData, 2016
The title compound, C14H12N4, has approximate twofold rotational symmetry. The pseudo-twofold axis bisects the C—C bonds of the dihydropyrazine ring, which has a screw–boat conformation.
Maciej Posel, Helen Stoeckli-Evans
doaj   +1 more source

Recent Progresses in the Catalytic Stereoselective Dearomatization of Pyridines

open access: yesMolecules, 2023
1,2- and 1,4-dihydropyridines and N-substituted 2-pyridones are very important structural motifs due to their synthetic versatility and vast presence in a variety of alkaloids and bioactive molecules.
Lucrezia Margherita Comparini   +1 more
doaj   +1 more source

Crystal structure of a new monoclinic polymorph of N-(4-methylphenyl)-3-nitropyridin-2-amine

open access: yesActa Crystallographica Section E, 2014
The title compound, C12H11N3O2, is a second monoclinic polymorph (P21, with Z′ = 4) of the previously reported monoclinic (P21/c, with Z′ = 2) form [Akhmad Aznan et al. (2010). Acta Cryst. E66, o2400].
Aina Mardia Akhmad Aznan   +3 more
doaj   +1 more source

Unraveling Bonding Mechanisms and Electronic Structure of Pyridine Oximes on Fe(110) Surface: Deeper Insights from DFT, Molecular Dynamics and SCC-DFT Tight Binding Simulations

open access: yesMolecules, 2023
The development of corrosion inhibitors with outstanding performance is a never-ending and complex process engaged in by researchers, engineers and practitioners. The computational assessment of organic corrosion inhibitors’ performance is a crucial step
Hassane Lgaz   +7 more
doaj   +1 more source

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