Results 51 to 60 of about 340,813 (275)
O,N,N-Pincer ligand effects on oxidatively induced carbon–chlorine coupling reactions at palladium [PDF]
, 2015 The syntheses of two families of sterically tuneable O,N,N pro-ligands are reported, namely the 2-(phenyl-2′-ol)-6-imine-pyridines, 2-(C6H4-2′-OH),6-(CMe[double bond, length as m-dash]NAr)C5H3N [Ar = 4-i-PrC6H4 (HL1a), 2,6-i-Pr2C6H3 (HL1b)] and the 2 ...
Cross, WB +4 more
core +1 more source
4D Printing of Self‐Immolative Polymers
Advanced Functional Materials, EarlyView.The integration of self‐immolative polymers (SIPs) into light‐based 3D printed structures is presented as a new “living” 4D printing strategy. By exploiting their metastability and stimuli‐responsiveness, SIP‐containing printed objects can undergo rapid and triggered degrowth under ambient conditions and subsequent regrowth through polymer ...
Johannes Markhart +3 more
wiley +1 more source
A Benchmark of GW Methods for Azabenzenes: Is the GW Approximation Good Enough?
, 2012 Many-body perturbation theory in the GW approximation is a useful method for describing electronic properties associated with charged excitations. A hierarchy of GW methods exists, starting from non-self-consistent G0W0, through partial self-consistency ...
Caruso, Fabio +8 more
core +1 more source
Concentration dependent tautomerism in green [Cu(HL1)(L2)] and brown [Cu(L1)(HL2)] with H2L1 = (E)-N’-(2-hydroxy-3-methoxybenzylidene)- benzoylhydrazone and HL2 = pyridine-4-carboxylic (isonicotinic) acid [PDF]
, 2011 The in situ formed hydrazone Schiff base ligand (E)-N’-(2-hydroxy-3-methoxybenzylidene)-benzoylhydrazone (H2L1) reacts with copper(II) acetate in ethanol in the presence of pyridine-4-carboxylic acid (isonicotinic acid, HL2) to green-[Cu(HL1)(L2)]・H2O ...
Ghorbanloo, Massomeh +5 more
core +1 more source
Using the Photostationary State of Arylazopyrazoles to Control Phase Transitions of Liquid Crystals
Advanced Functional Materials, EarlyView.A series of new arylazopyrazole photoswitches is designed as dopants for liquid crystalline materials. Unprecedented, the distribution of photoisomers at the photostationary state upon irradiation with light of specific wavelengths (365, 460, 520 nm) is used to control the liquid crystalline phase transitions under isothermal conditions, including ...
Tobias Thiele +3 more
wiley +1 more source
Advanced Functional Materials, EarlyView.In this study, the preparation techniques for silver‐based gas diffusion electrodes used for the electrochemical reduction of carbon dioxide (eCO2R) are systematically reviewed and compared with respect to their scalability. In addition, physics‐based and data‐driven modeling approaches are discussed, and a perspective is given on how modeling can aid ...
Simon Emken +6 more
wiley +1 more source
Chiral Nanohoops as an Efficient Spin Polarization System
Advanced Functional Materials, EarlyView.Chiral conjugated nanohoops with a central dibenzopentalene unit exhibit 90% spin polarization at low voltage and high conductivity. These properties make them ideal components in molecular spintronics applications. Abstract A central challenge in molecular spintronics is to achieve a high spin polarization at low operating voltages and ambient ...
Anu Gupta +4 more
wiley +1 more source
Icilio Guareschi and his amazing “1897 reaction”
Beilstein Journal of Organic Chemistry, 2021 Organic chemistry honors Icilio Guareschi (1847–1918) with three eponymic reactions, the best known ones being the Guareschi synthesis of pyridones and the Guareschi–Lustgarten reaction. A third Guareschi reaction, the so-called “Guareschi 1897 reaction”,
Gian Cesare Tron +4 more
doaj +1 more source
Proton-Electron Hyperfine Coupling Constants of the Chlorophyll a Cation Radical by ENDOR Spectroscopy [PDF]
, 1977 In this paper we describe the assignment of the major coupling constants in monomer chlorophyll a cation free radical by ENDOR spectroscopy. To facilitate chemical manipulation methylpyrochlorophyllide a has been used as a stand-in, and a suite of six ...
Katz, J. J., Norris, J. R., Scheer, Hugo
core +1 more source
Advanced Functional Materials, EarlyView.The catalytic valorization of biomass represents an essential approach for achieving sustainable chemical production, with formic acid (FA) being recognized as a valuable platform chemical for hydrogen storage and environmentally friendly synthetic applications.
Yiqi Geng +6 more
wiley +1 more source