Effects of solvent and structure on the reactivity of 6-substituted nicotinic acids with diazodiphenylmethane in aprotic solvents [PDF]
The rate constants for the reactions of diazodiphenylmethane (DDM) with 6-substituted nicotinic acids in aprotic solvents at 30°C were determined. The obtained second order rate constants in aprotic solvents, together with literature data for benzoic and
Drmanić Saša Ž. +2 more
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The effects of solvents and structure on the electronic absorption spectra of the isomeric pyridine carboxylic acid N-oxides [PDF]
The ultraviolet absorption spectra of the carboxyl group of three isomeric pyridine carboxylic acids N-oxides (picolinic acid N-oxide, nicotinic acid N-oxide and isonicotinic acid N-oxide) were determined in fourteen solvents in the wavelength range ...
Drmanić Saša Ž. +4 more
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2-(Carboxymethylsulfanyl)pyridine-3-carboxylic acid monohydrate [PDF]
The title compound, C(8)H(7)NO(4)S·H(2)O, was obtained by reaction of 2-mercaptopyridine-3-carboxylic acid with chloro-acetic acid. In the mol-ecular structure, the dihedral angle between the two least-squares planes defined by the pyridine ring and the carb-oxy group is 8.32 (9)°.
Xiao-Juan Wang, Yun-Long Feng
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Facile Synthesis of Some Novel Pyrido[3', 2': 4, 5]thieno[2,3-b][1,4]thiazine-8-carboxylic Acids
Model tetrahydropyrido[3',2':4,5]thieno[2,3-b][1,4]thiazines 9a-c were synthesized via reductive lactamization, using sodium dithionite, of the respective 2-[(carboxyalkyl)thio]-3-nitro-4,7-dihydrothieno[2,3-b]pyridine-5-carboxylic acids 7a-c. The latter
Salim S Sabri +4 more
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A Simple Method for Synthesis of Active Esters of Isonicotinic and Picolinic Acids
A method for preparation of the p-nitrophenyl-, N-hydroxysuccinimidyl- and pentafluorophenyl esters of isonicotinic and picolinic acids from the corresponding acids is reported.
Jørn B. Christensen
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Natural phenol and phenolic acids are widely distributed in the plant kingdom and the major dietary sources include fruits and beverages derived therefrom.
Alessio Incocciati +4 more
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Reaction of Pyridine Bases with Carboxylic Acids in Benzene [PDF]
Abstract The reaction of pyridine bases with aliphatic monocarboxylic acids has been studied by means of the partition method. Partition was carried out at 25 °C between benzene and 0.10 mol dm−3 (Na, H) ClO4 aqueous solution, the total concentration of pyridine base and that of carboxylic acid being less than 2×10−2 mol dm−3 and 1.0 mol
Katsumi Hirose, Motoharu Tanaka
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Synthesis, structural characterization and antimicrobial evaluation of some novel piperidin-4-one oxime esters [PDF]
Fifteen novel biologically active piperidin-4-one oxime esters (8-22) have been synthesized with good yields. These compounds were prepared from in-situ activated carboxylic acids using POCl3 and pyridine with piperidin-4- one oximes.
Krishnan Gokula K. +2 more
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The effect of aliphatic carboxylic acids on olfaction-based host-seeking of the malaria mosquito Anopheles gambiae sensu stricto [PDF]
The role of aliphatic carboxylic acids in host-seeking response of the malaria mosquito Anopheles gambiae sensu stricto was examined both in a dual-choice olfactometer and with indoor traps.
Yu Tong Qiu +10 more
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Cobalt-Catalyzed Tandem Deamination, Decarboxylation, and Dehomologation of Primary Amines to Carboxylic Acids in Water [PDF]
Selective transformation of carboxylic acids through oxidative deamination of primary amines is a catalytically challenging and useful transformation. Herein, we present a simple protocol for the transformation of primary amines to carboxylic acids with ...
Deep, Chowdhury, Arup, Mukherjee
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