Results 101 to 110 of about 22,841 (254)

Bis-isoquinolinium and bis-pyridinium acetylcholinesterase inhibitors: in vitro screening of probes for novel selective insecticides

open access: yes, 2017
Library screening of pyridinium-based compounds, acting as acetylcholinesterase inhibitors, for their potential insecticidal efficacy.
Eugenie Nepovimova   +10 more
core   +1 more source

FLP Mediated Conversion of Difluorobenzylalkynes to Fluoroallenyl Oniums via an SN1’ Pathway

open access: yesChemistry – A European Journal, EarlyView.
Frustrated Lewis pair (FLP) selective C‒F activation of difluorobenzylalkynes allows the formation of fluoroallenic oniums via an SN1’ substitution pathway. The fluoroallenic onium salts are synthetic precursors that allow subsequent functionalization at allenic and onium positions.
Max Coles   +6 more
wiley   +1 more source

Stereoretentive Nucleophilic Aromatic Substitution Accesses Atropisomeric 4‐Amino‐N‐Arylquinolinium Salts

open access: yesChemistry – A European Journal, EarlyView.
Quinolin‐4‐ones were converted to chloroquinolinium salts, allowing formation of axially chiral aminoquinolinium salts via an enantioretentive SNAr reaction with a variety of amine nucleophiles. The salts have a high rotational barrier, with a racemization half‐life of ∼1000s of years.
Darren Holmes   +5 more
wiley   +1 more source

O Papel da agua (ou a sua ausencia) na formação de compostos ricos em energia nos sistemas biologicos [PDF]

open access: yes, 1997
Tese (Mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas.Uma das questões mais fascinantes que já foram levantadas pelos pesquisadores nas últimas décadas refere-se ao estudo dos compostos ricos em energia, tais ...
Machado, Vanderlei Gageiro
core  

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

open access: yesChemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

Synthesis of naphthoquinone derivatives with some study on percentage rate of formation for pyridinium salt / Nor Shazana Mohamed Daud [PDF]

open access: yes, 2010
The focus of this study is to synthesize the naphthoquinone derivative via the reaction of pyridinium salt with methyl naphthoquinone. The starting material 2,4-dibromoacetophenone reacted with pyridine to produce pyridinium salt in 96.29% yield.
Mohamed Daud, Nor Shazana
core  

Detection of Testosterone Esters in Urine: Evidence of Trace‐Level Detectability in Doping Control Samples

open access: yesDrug Testing and Analysis, EarlyView.
An ultrasensitive LC‐MS/MS method for detecting testosterone esters (T‐esters) in urine at sub–pg/mL levels is presented. This approach, employing Girard P derivatization, provides the first evidence of T‐esters' trace‐level detectability in human urine.
Daniel Pecher   +3 more
wiley   +1 more source

All‐in‐One Intelligent Hemostatic Sponge: Rapid Hemostasis for Non‐Compressive Wounds With Synergetic Enhanced Antibacterial Efficacy and Self‐Reporting Biodegradation

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Clinicians often concurrently tackle critical challenges including emergency hemorrhage, secondary infection, and the elusive tracking of biodegradation of conventional hemostatic agents for complex wounds. Here, we report an intelligent hemostatic sponge (spCS@AIE) by incorporating aggregation‐induced emission (AIE) nanoparticles with short‐wave ...
Zhicheng Liu   +12 more
wiley   +1 more source

Tellurium Electrochemistry: From Mechanistic Analysis in Diverse Electrolytic Media to Advanced Energy Storage Applications

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
As a metalloid with broad prospects in advanced applications, Te has not been fully clarified in terms of its intricate electrochemical behaviors across varied systems. This review systematically integrates fundamental electrochemical mechanisms, reaction kinetics identifications, and device application insights, establishing a comprehensive framework ...
Meng Zhang   +6 more
wiley   +1 more source

Push-pull systems based on pyridinium betaines.

open access: yes, 2012
Byla provedena literarni rešerše mapujici využiti a synteticke postupy vedouci k push-pull systemům na bazi pyridinium betainů. Využiti těchto latek spočiva předevšim v jejich NLO vlastnostech.
Miklík, David
core  

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