Structural and Spectroscopic Evidence of Hydrogen Bonded Anionic Wires in Protic Ionic Liquids
Anionic wires of deprotonated carboxylic acids challenge the general wisdom that like charges repel. The hydrogen bond motif observed in the X‐ray structure is even preserved in the liquid state of the material as shown by δ1H NMR spectroscopy. The experimental and theoretical findings provide deep insight into the nature of hydrogen bonding.
Maham Azhar +5 more
wiley +1 more source
Encapsulation of Porphyrins in Polymer Microgels and Microbeads for Heterogeneous Photooxidation
Amino‐ or ammonium‐functionalized tetraphenylporphyrins were synthesized and encapsulated within polymers to form microgels and microbeads that act as heterogeneous photocatalysts. Photooxidation in aqueous media quantitatively converts sulfides and aldehydes into sulfoxides and carboxylic acids via the singlet‐oxygen pathway, demonstrating an ...
Imogen Smith +3 more
wiley +1 more source
Photochemical Reaction Discovery Enabled by the Dynamic Speciation of Copper Complexes
A strategy for accelerated photochemical reaction discovery is reported that harnesses the dynamic speciation of copper complexes, driven by their labile metal–ligand bonds. This platform simplifies reaction screening by combining an earth‐abundant copper(II) salt with commercially available ligands, which reversibly generate multiple catalytic species
Alessio Regni +6 more
wiley +2 more sources
Design and synthesis of carbazole-acrylamide-pyridinium hybrids as dual acetylcholinesterase/butyrylcholinesterase inhibitors and evaluation of their cytotoxic profile on SH-SY5Y and HEK293 cell lines. [PDF]
Taherkhani AM +12 more
europepmc +1 more source
Photosensitizing Au(I) Catalysis With Coumarins
A Au(I) complex with a tethered coumarin fragment was synthesized and characterized by UV‐vis and emission spectroscopy. Its ability to facilitate photo‐driven cross‐coupling reactions through single‐electron and energy transfer events was evaluated. ABSTRACT Gold catalysis shows versatility in a wide range of challenging transformations, wherein light‐
Liliana Capulín Flores +2 more
wiley +1 more source
The Expanding Role of Diazirines in Synthetic Methodology
Beyond their established role in photoaffinity labeling, diazirines have emerged as versatile reagents in synthetic chemistry. This review highlights their dual reactivity as carbene and nitrogen‐transfer precursors, showcasing mechanistic insights and diverse applications in cyclopropanations, cycloadditions, skeletal editing, amination, heterocycle ...
Viktor Savic +3 more
wiley +1 more source
Rationalizing (in)stability of pyridinium ketones in aqueous organic flow batteries. [PDF]
Gonzalez G +9 more
europepmc +1 more source
The Redox Activity of Two Identical Units on Xylylene-Bridged <i>N</i>‑Pyridinium-Substituted Diamino-1,3,5-triazine. [PDF]
Thangavel A +5 more
europepmc +1 more source
Efficient and versatile supramolecular functionalization of polysilicon microchips with cationic amphiphile salts for incorporation of therapeutics. [PDF]
Alea-Reyes ME +4 more
europepmc +1 more source
Solvate ionic liquids lubrication reduced the coefficient of friction by ∼60% compared to dry sliding, reaching steady‐state values as low as 0.04–0.05. Corrosion weight‐loss measurements in 1 M HCl further demonstrated significant inhibition behavior, with only 100 ppm of [Li(G3)][TFSI] (∼68.5 μL/L) reducing corrosion‐product weight loss by 63 ...
Sameh Dabees +6 more
wiley +1 more source

