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Stereoselective polar radical crossover for the functionalization of strained-ring systems. [PDF]
Trauner F+4 more
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Zn(OTf)2-catalyzed intra- and intermolecular selenofunctionalization of alkenes under mild conditions. [PDF]
Qi C+5 more
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Depression Symptoms in Patients with Cystic Fibrosis Fluctuate at Baseline and Improve with Elexacaftor/Tezacaftor/Ivacaftor Therapy. [PDF]
Piehler L+5 more
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Hypervalent iodine-mediated cyclization of bishomoallylamides to prolinols. [PDF]
Butt SE+3 more
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Pulse Radiolysis of Pyrrolidine
Radiation Research, 1970The formation, decay, and absorption spectra of transients formed from pyrrolidine in aqueous solutions were studied. The solvated electron ( ${\rm e}_{{\rm aq}}^{-}$) reacts with the protonated and the nonprotonated pyrrolidine forming the ${\rm C}_{4}{\rm H}_{8}{\rm N}$· radical. The rate constants are: $k({\rm e}_{{\rm aq}}^{-}+{\rm C}_{4}{\rm H}_{8}
N. Getoff, F. Schwörer, F. Schworer
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Synthesis of Fluoropyrrolidines and (Fluoroalkyl)pyrrolidines [PDF]
Pyrrolidines and their derivatives are of great interest in medicinal chemistry and organic synthesis. Fluoropyrrolidines and (fluoroalkyl)pyrrolidines have been utilized in the preparation of medicinal drugs and also as organocatalysts. The synthesis of such compounds is achieved through the fluorination of pyrrolidine derivatives or by multistep ...
Lequeux, Thierry, Pfund, Emmanuel
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ChemInform, 1993
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Mahboobi, Siavosh+3 more
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AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Mahboobi, Siavosh+3 more
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Diastereoselective Preparation of Azetidines and Pyrrolidines [PDF]
Iodine-mediated cyclization of homoallyl amines at room temperature delivered cis-2,4-azetidine through a 4-exo trig cyclization. Isomerization of iodo-azetidines to cis-pyrrolidines could be achieved by heating, with complete stereocontrol. The relative stereochemistry of the iodo-azetidines and pyrrolidines was confirmed by NMR spectroscopy and X-ray
John S. Fossey+2 more
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Telescoped Synthesis of Stereodefined Pyrrolidines
Organic Letters, 2013Telescoped and one-pot olefination/asymmetric functionalization approaches to disubstituted pyrrolidines (dr up to 99:1, up to 99% ee) have been developed using commercially available tetramisole (0.1 to 5 mol %). Using OTMS-quinidine as the Lewis base gives preferential access to an anti-configured pyrrolidine in high enantioselectivity.
Dorine Belmessieri+3 more
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The microwave spectrum of pyrrolidine
Journal of Molecular Spectroscopy, 1984Abstract The rotational spectra of the normal and N-D isotopic species of pyrrolidine have been measured. The molecule exists in an envelope conformation, with the nitrogen atom out of the plane containing the carbon atoms and with the imino hydrogen in the axial position.
Heinz Oberhammer+4 more
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