Results 41 to 50 of about 111,785 (320)

Variational phase recovering without phase unwrapping in phase-shifting interferometry [PDF]

open access: yes, 2020
We present a variational method for recovering the phase term from the information obtained from phase-shifting methods. First we introduce the new method based on a variational approach and then describe the numerical solution of the proposed cost function, which results in a simple algorithm.
arxiv   +1 more source

Generation of superoxide and singlet oxygen from α-tocopherolquinone and analogues. [PDF]

open access: yes, 2007
Three potential routes to generation of reactive oxygen species from a tocopherolquinone have been identified. The quinone of the water-soluble vitamin E analogue Trolox C (Trol-Q) is reduced by hydrated electron and isopropanol a hydroxyalkyl radical ...
Bisby, RH   +4 more
core   +1 more source

Poly(1,4‐anthraquinone) as an Organic Electrode Material: Interplay of the Electronic and Structural Properties due to the Unusual Lone‐Pair‐π Conjugation

open access: yesAdvanced Functional Materials, Volume 35, Issue 12, March 18, 2025.
In this study, the unique role of the unusual lone‐pair‐π conjugation mechanism in poly(1,4‐anthraquinone) (P14AQ) is explored as an organic electrode material. Unlike traditional π‐π interactions, P14AQ's conjugation involves lone pairs of oxygen atoms interacting with the π cloud of adjacent units, enabling stable charge transport even with minimal π‐
Xiaotong Zhang, Piotr de Silva
wiley   +1 more source

About a Proposition on Escobar's paper "The Geometry of the First Non-zero Stekloff Eigenvalue" [PDF]

open access: yesarXiv, 2023
Let $(M^{2},g_{0})$ be a compact manifold with boundary, and let $g$ and $g_{0}$ be conformally related by $g=e^{2f}g_{0}$. We show that the inequality $$\nu_{1}(g)\geq\Big(\max_{x\in\partial M}e^{-f(x)}\Big)\nu_{1}(g_{0})$$ stated in Proposition 2 in [1], is only possible when the equality is achieved. In order to achieve such equality, it is required
arxiv  

Deciphering the Origin of Higher Shell Coordination on Single Iron Catalysts for Resilient Modulating Persulfate Oxidation Into Singlet Oxygen Pathway

open access: yesAdvanced Functional Materials, Volume 35, Issue 12, March 18, 2025.
This study reveals that higher shell S coordination can effectively modulate the spin state of FeN4 site via long‐range electronic interactions, giving rise to the oriented generation of singlet oxygen from peroxymonosulfate activation. Abstract Precise manipulation of coordination structure of single‐atom sites and establishment of schematic ...
Liang Zhang   +8 more
wiley   +1 more source

Physiological Evidence for Isopotential Tunneling in the Electron Transport Chain of Methane-Producing Archaea [PDF]

open access: yes, 2017
Many, but not all, organisms use quinones to conserve energy in their electron transport chains. Fermentative bacteria and methane-producing archaea (methanogens) do not produce quinones but have devised other ways to generate ATP. Methanophenazine (MPh)
Buan, Nicole R., Duszenko, Nikolas
core   +1 more source

Reductive activation of potential antitumor bis(aziridinyl)benzoquinones by xanthine oxidase: Competition between oxygen reduction and quinone reduction [PDF]

open access: yes, 1990
The reduction of a series of 2,5-bis(1-aziridinyl)-1,4-benzoquinone (BABQ) derivatives with various 3,6 substituents by the enzyme xanthine oxidase has been studied.
Janssen, L.H.M.   +5 more
core   +3 more sources

Stable Radical Polymers as New Electroactive Materials: Synthesis, Properties, and Emerging Applications

open access: yesAdvanced Functional Materials, EarlyView.
This review covers the recent advances in the synthesis and properties of stable radical polymers (SRPs) and presents their applications in electronics, magnetics, optoelectronics, and biomedicines. The review concludes with a discussion of the challenges in radical chemistry and functionalization, while shedding light on the groundbreaking potential ...
Yufeng Xiong   +11 more
wiley   +1 more source

A Simulated Patient Encounter of Status Epilepticus

open access: yesMedEdPORTAL, 2008
Introduction Status epilepticus secondary to an isoniazid overdose is life threatening. We created this high-fidelity simulation for emergency medicine residents and medical students to practice the recognition and management of life threatening status ...
Joshua Quinones
doaj   +1 more source

A Computational Protocol Combining DFT and Cheminformatics for Prediction of pH-Dependent Redox Potentials

open access: yesMolecules, 2021
Discovering new materials for energy storage requires reliable and efficient protocols for predicting key properties of unknown compounds. In the context of the search for new organic electrolytes for redox flow batteries, we present and validate a ...
Rocco Peter Fornari, Piotr de Silva
doaj   +1 more source

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