Results 121 to 130 of about 1,080 (176)
Some of the next articles are maybe not open access.
THE CHEMISTRY OF QUINUCLIDINE DERIVATIVES
Russian Chemical Reviews, 1960CONTENTS I. Introduction 38 II. Quinuclidine 38 III.
M V Rubtsov, E E Mikhlina, L N Yakhontov
openaire +1 more source
Russian Chemical Reviews, 1969
The review deals with the chemical properties and the biological activity of the derivatives of 1-azabicyclo[2,2,2]octane widely known as quinuclidine. The work of the Soviet School of Chemists, founded by M.V.Rubtsov, in the field of quinuclidine derivatives is reviewed in detail.
openaire +1 more source
The review deals with the chemical properties and the biological activity of the derivatives of 1-azabicyclo[2,2,2]octane widely known as quinuclidine. The work of the Soviet School of Chemists, founded by M.V.Rubtsov, in the field of quinuclidine derivatives is reviewed in detail.
openaire +1 more source
Chemischer Informationsdienst, 1978
AbstractDie Chinuclidin‐2‐ (II) und ‐3‐carbonsäureamide (III) wurden durch Kondensation des Säurechlorids (I) bzw. des isomeren 3‐Chlorcarbonyl‐Derivats mit den entsprechenden Aminen erhalten.
S. BINIECKI, B. PROKOPCZYK
openaire +1 more source
AbstractDie Chinuclidin‐2‐ (II) und ‐3‐carbonsäureamide (III) wurden durch Kondensation des Säurechlorids (I) bzw. des isomeren 3‐Chlorcarbonyl‐Derivats mit den entsprechenden Aminen erhalten.
S. BINIECKI, B. PROKOPCZYK
openaire +1 more source
The structure of dimethylbis(quinuclidine)beryllium
Journal of Organometallic Chemistry, 1971Abstract The structure of (CH3)2Be·2NC7H13 has been determined by single-crystal X-ray diffraction methods. Four monomeric molecules crystallize in a monoclinic unit cell of dimensions a = 11.82±0.02, b = 12.71±0.02, c = 12.00±0.02 A, and β = 113.1°±0.3°. The space group is P21/c.
C.D. Whitt, J.L. Atwood
openaire +1 more source
Stereocontrolled approach to quinuclidine derivatives
Tetrahedron Letters, 1998Abstract Asymmetric Michael-type cyclization of chiral enamino ester (S)-7 furnished the quinuclidinone derivative (3R, 4S)-5, with a high degree of stereoselectivity.
Alexandre J. Da Silva Goes +2 more
openaire +1 more source
Chemistry of Heterocyclic Compounds, 1972
The tautomerism of 2-ethoxycarbonyl-3-oxoquinuclidine and 2-ethoxycarbonyl-3-oxobenzo-[b]quinuclidine was investigated by means of IR and UV spectra and potentiometric titration. It was found that tautomeric equilibrium between the ketone, enol, and internally ionized forms is realized for 2-ethoxycarbonyl-3-oxoquinuclidine, and the position of the ...
Yu. N. Sheinker +6 more
openaire +1 more source
The tautomerism of 2-ethoxycarbonyl-3-oxoquinuclidine and 2-ethoxycarbonyl-3-oxobenzo-[b]quinuclidine was investigated by means of IR and UV spectra and potentiometric titration. It was found that tautomeric equilibrium between the ketone, enol, and internally ionized forms is realized for 2-ethoxycarbonyl-3-oxoquinuclidine, and the position of the ...
Yu. N. Sheinker +6 more
openaire +1 more source
Mass spectra of the substituted quinuclidines
Organic Mass Spectrometry, 1970AbstractThe mass spectra of the quinuclidine‐2 (and ‐3)‐ones and other functional derivatives of quinuclidine as well as 2‐azaquinuclidine and benzoquinuclidine have been investigated. The fragmentation through the open form of the molecular ion and the applicability of Bredt's rule to amine fragmentation of the bridgehead nitrogen bicyclic systems are
R. G. Kostyanovsky +3 more
openaire +1 more source
Novel heterocyclic derivatives of quinuclidine
Journal of Heterocyclic Chemistry, 1967AbstractTreatment of ethyl 3‐quinuclidinone‐2‐carboxyIate (III) with appropriate reagents gave 2,3‐fused heterocycles including pyrazolol, aminopyrimidinone, and aminopyridazinone types. The thiourea derivative of III could not be cyclized. Triazoline, pyrazoline, and isoxazoline derivatives were prepared by 1,3‐dipolar cycloadditions to the 2‐ and 3 ...
William A. Renters +2 more
openaire +1 more source
New derivatives of quinuclidine as potential antihypertensive agents
Journal of Pharmaceutical Sciences, 1967Five new 3-aminoalkoxy derivatives of quinuclidine have been synthesized. All compounds reduced blood pressure in dogs to varying degrees, the most effective being 3-(3-dimethylaminopropoxy) quinuclidine. The evidence points to ganglionic blockade as the principal mechanism of action with the possibility that it may also be due to some direct ...
L L, Collins, C A, Papacostas, S, Elkin
openaire +2 more sources
Syntheses and Structures of Quinuclidine-Stabilized Amido- and Azidogallanes
Inorganic Chemistry, 2000Quinuclidine-stabilized amido- and azidogallanes, HGa[N(TMS)2]2(quin) (1), H2Ga[N(TMS)2](quin) (2), HGa-[N(H)(2,6-iPr2C6H3)]2(quin) (3), and H2GaN3(quin) (4), were synthesized from the quinuclidine adducts of mono- and dichlorogallane. Structural determinations revealed that all compounds were monomeric with four-coordinate gallium centers.
B, Luo, V G, Young, W L, Gladfelter
openaire +2 more sources

