Results 11 to 20 of about 953 (169)

Biological activity of monoquaternary ammonium compounds based on 3-substituted quinuclidine: A short review [PDF]

open access: yes, 2020
Quaternary ammonium compounds (QACs) have a long-known application as antiseptics and disinfectants applied in various industries such as pharmaceutical, agricultural and food industry.
Renata Odžak, Matilda Šprung
core   +1 more source

Electron Donor–Acceptor Complex Catalysis in Synthetic Chemistry

open access: yesAngewandte Chemie, EarlyView.
Electron donor–acceptor (EDA) complexes are moving beyond stoichiometric photoactivation toward catalytic platforms for radical generation. Productive EDA catalysis requires coordinated donor–acceptor association, charge‐transfer excitation, radical reactivity, and vcatalyst turnover.
Tristan von Münchow   +3 more
wiley   +2 more sources

Remapping the Synthetic Landscape of α‐Tertiary Alkylamines via Dual‐Functional Catechol

open access: yesAngewandte Chemie, Volume 138, Issue 37, 7 September 2026.
A three‐component assembly strategy has been developed for the modular synthesis of hindered α‐tertiary aliphatic amines from readily available precursors through unlocking the dual role of catechol. The practicality of this methodology has been demonstrated in over 90 examples, including compounds that are otherwise difficult to access, along with ...
Chen‐Yan Cai, Yuzuru Kanda, Tian Qin
wiley   +2 more sources

Bond Length as a Unified Descriptor for Stable Iodine Battery

open access: yesAngewandte Chemie, Volume 138, Issue 36, 1 September 2026.
Charge transfer induced by the interactions between iodine and ligands leads to the elongation of the I–I bond. This resulting bond length correlates directly with coordination strength, serving as a unified descriptor for the rational design of both cathode hosts and electrolyte components.
Mengzi Geng   +9 more
wiley   +2 more sources

A Diastereoselective Radical Cyclization Approach to Substituted Quinuclidines

open access: yes, 2016
A new, concise, and flexible approach to novel quinuclidines has been developed, which employs a phosphorus hydride mediated radical addition/cyclization reaction in the key step.
Thomas A. Hunt (2642518)   +2 more
core   +1 more source

Precision Switching and Coupled Motion in a [3]Rotaxane Molecular Machine

open access: yesAngewandte Chemie, Volume 138, Issue 34, 17 August 2026.
A [3]rotaxane, composed by two crown ether macrocycles and an axle presenting three recognition sites, is operated through both chemical and electrochemical stimuli. The position of the macrocycles is precisely controlled by sequential stimulation and the processes are fully reversible. The characterization of the system revealed the macrocycles affect
Leonardo Andreoni   +3 more
wiley   +2 more sources

A Selectfluor‐based Polonovski Rearrangement Leading to Novel Entities for Synthetic and Medicinal Applications

open access: yesChemistry – A European Journal, EarlyView.
Starting from carboxylic acids and Selectfluor‐derivatives, functionalized diazabicyclooctanes can be obtained via a novel Polonovski‐type rearrangement proceeding under mild reaction conditions. Besides their use in organic synthesis the unique structure and reactivity of the rearrangement products enables applications in medicinal chemistry ...
Jakob Kuhn   +5 more
wiley   +1 more source

Kinetic and mechanistic studies on quinuclidinolysis of Y-substituted-phenyl picolinates: Effect of amine nature on reactivity and transition- state structure

open access: yes, 2018
Second-order rate constants (k<inf>N</inf>) have been measured spectrophotometrically for reactions of Y-substitutedphenyl picolinates (7a-7i) with a series of quinuclidines in 80 mol% H<inf&amp ...
엄익환
core   +1 more source

Diorganotelluride···N Chalcogen Bonds: Analysis and Tuning of Two σ‐Holes

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
Two new chalcogen bond aggregates were analyzed using single crystal X‐ray diffraction: an oligomeric ChB aggregate between bis(pentafluorophenyl) telluride and DABCO, and a monoadduct between (pentafluorophenyl)(phenyl) telluride and quinuclidine. In addition to some of the shortest intermolecular Te···N contacts reported, these structures provide ...
Thokozire Sweetland   +5 more
wiley   +1 more source

Change in Rate-Determining Step in an E1cB Mechanism during Aminolysis of Sulfamate Esters in Acetonitrile

open access: yes, 2016
The kinetics of the reactions of the nitrogen−sulfur(VI) esters 4-nitrophenyl N-methylsulfamate (NPMS) with a series of pyridines and a series of alicyclic amines and of 4-nitrophenyl N-benzylsulfamate (NPBS) with pyridines, alicyclic amines, and a ...
Paul McGrath (3030237)   +3 more
core   +1 more source

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