Results 161 to 170 of about 89,874 (280)

2,3‐Dichloro‐5,6‐Dicyano‐1,4‐Benzoquinone (DDQ)‐Mediated CC Bond Formation: Redox Strategies from Stoichiometric to Catalytic Systems

open access: yesChemistryOpen, EarlyView.
2,3‐Dichloro‐5,6‐dicyano‐1,4‐benzoquinone serves as a versatile oxidant and redox catalyst for CC bond formation through hydride abstraction or single‐electron transfer. Stoichiometric and catalytic systems enable benzylic, allylic, and aromatic CH activation under mild, metal‐free conditions, providing sustainable routes to complex and bioactive ...
Dohoon Cha, Sun‐Joon Min
wiley   +1 more source

Tuning adsorption and morphology in poly(glutamic acid) via controlled acidic partial deprotection

open access: yesPolymer International, EarlyView.
Partial deprotection of poly(glutamic acid) generates morphologies and assemblies that match fully deprotected polypeptides in small‐molecule adsorption, extending to block copolypeptides with pH‐dependent effects. Abstract Synthetic polypeptides prepared from N‐carboxyanhydride (NCA) monomers are important platforms for environmental and medical ...
Hunter Wood   +5 more
wiley   +1 more source

Host tree preference and performance of the Eurasian spruce bark beetle (Ips typographus) on Scots pine

open access: yesPest Management Science, EarlyView.
Ips typographus showed lower reproductive output in an occasional host (Pinus sylvestris) under laboratory conditions, and did not prefer its main host (Picea abies) over P. sylvestris in two‐choice bioassays. Abstract BACKGROUND The Eurasian spruce bark beetle, Ips typographus, is one of the most serious pests of Norway spruce (NS, Picea abies), with ...
Jana Gabriele Burchards   +2 more
wiley   +1 more source

Molecular basis and biological relevance of bacterial and plant pinoresinol/lariciresinol reductase specificities. [PDF]

open access: yesProtein Sci
Smith CA   +7 more
europepmc   +1 more source

The continuing significance of chiral agrochemicals

open access: yesPest Management Science, Volume 81, Issue 4, Page 1697-1716, April 2025.
In the time frame 2018–2023, around 43% of the 35 chiral agrochemicals introduced to the market (herbicides, fungicides, insecticides, acaricides, and nematicides) contain one or more stereogenic centers in the molecule, and almost 69% of them have been marketed as racemic mixtures of enantiomers or stereoisomers.
Peter Jeschke
wiley   +1 more source

Enantiopurity‐Dependent Peptide Coacervates and Asymmetric Organocatalysis

open access: yesSmall, EarlyView.
Enantiopure peptide LLLPFF‐OCH3 forms liquid–liquid phase‐separated (LLPS) droplets that act as chiral microreactors for enantioselective aldol catalysis. Racemic mixtures fail to undergo LLPS, showing spontaneous enantiomeric self‐disproportionation (SDE).
Alice Vetrano   +21 more
wiley   +1 more source

Designing Tailored Molecular Cavities Using Calix[5]arenes as Building Blocks

open access: yesThe Chemical Record, EarlyView.
This account focuses on the shape and dimensions of cavities formed by precisely designed molecular frameworks. It highlights our efforts to construct synthetically tailored cavities based on calix[5]arenes. This study examines the shapes and dimensions of cavities defined by well‐designed molecular structures.
Takehiro Hirao, Takeharu Haino
wiley   +1 more source

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