Results 161 to 170 of about 53,376 (301)

Formation of Bicyclic Skeletons by Aerobic, Manganese‐Mediated Cyclization of β‐Oxoesters

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Manganese(III) promotes aerobic radical cyclization reactions of β‐oxoesters with an ω‐alkenyl side chain at the β’‐position to give bicyclic products with a 1,4‐dicarbonyl structure. Bicyclic perhydro‐pentalene, ‐indene, and ‐azulene, as well as decaline skeletons were accessed by aerobic manganese(III)‐mediated radical cyclizations of cyclic β ...
Julian Friedrich   +2 more
wiley   +1 more source

Advances in Enantioselective Synthesis and Chiral Resolution of Insecticides. [PDF]

open access: yesMolecules
López-Rosas CA   +4 more
europepmc   +1 more source

Probing Chiral Recognition on Amylose Tris(3,5‐Dimethylphenylcarbamate) Using Cinnamyl 2‐Aminoanilides: The Subtle Impact of Aliphatic Substituents

open access: yesELECTROPHORESIS, EarlyView.
This study investigates how subtle aliphatic substituent differences in racemic cinnamyl 2‐aminoanilides affect chiral recognition on amylose tris(3,5‐dimethylphenylcarbamate). Pronounced enantioselectivity changes arose from minimal structural variations. Mobile phase effects were examined, with 2‐propanol improving resolution.
Selen Gözde Kaya   +5 more
wiley   +1 more source

Cyclodextrins as Chiral Selectors in Capillary Electrophoresis—Recent Developments in Understanding Analyte Complexation and Applications in Pharmaceutical Analysis

open access: yesELECTROPHORESIS, EarlyView.
Cyclodextrins are the most often applied chiral selectors in CE enantioseparations. In combination with NMR spectroscopy and molecular modeling, studies for an understanding of chiral recognition underlying enantioseparations have been performed.
Gerhard K. E. Scriba
wiley   +1 more source

Protein‐Based High‐Performance Liquid Chromatography and Cyclodextrin‐Capillary Electrokinetic Chromatography for the Chiral Separation of Azoles

open access: yesELECTROPHORESIS, EarlyView.
Human serum albumin‐based high‐performance liquid chromatography and cyclodextrin‐based capillary electrokinetic chromatography were used for the chiral separation of azoles. Although only two of the five tested azoles could be enantioseparated by liquid chromatography, all of them were separated by capillary electrokinetic chromatography using single ...
Sarah Moreau   +3 more
wiley   +1 more source

Application, Challenges, and Prospects of Non‐Thermal Processing Technologies for Seaweed Protein Extraction—A Review

open access: yesFood Chemistry International, EarlyView.
This review highlights non‐thermal extraction technologies for seaweed proteins, emphasizing their mechanisms, impacts on protein structure and functionality, and sustainability potential. Key limitations related to species dependence, extract complexity, and scale‐up are discussed to guide future industrial and biorefinery applications.
Rahat Mahmud   +3 more
wiley   +1 more source

Chiral perovskites for next‐generation chiral optoelectronics and spintronics

open access: yesFlexMat, EarlyView.
Benefiting from structural inversion symmetry breaking and strong spin‐orbit coupling, chiral perovskites possess intriguing chiral optical and spin properties. We overview their advances and core applications in perovskite solar cells, circularly polarized light detectors and spin circularly polarized‐light‐emitting diodes, offering great potential ...
Mengyao Zhang   +13 more
wiley   +1 more source

Home - About - Disclaimer - Privacy