Results 31 to 40 of about 1,098,861 (293)

Are rate constants constant?

open access: yesThe Journal of Physiology, 2006
In this issue of The Journal of Physiology, Uebachs et al. (2006) report a seemingly simple observation: the rate of recovery from inactivation of CaV3 (T-type) calcium channels depends on the length of the depolarization that produced the inactivation. Why is this heretical? A basic principle of chemical kinetics is that rate constants are constant.
openaire   +3 more sources

Rate constants for diffusive processes by partial path sampling

open access: yes, 2003
We introduce a path sampling method for the computation of rate constants for systems with a highly diffusive character. Based on the recently developed algorithm of transition interface sampling (TIS) this procedure increases the efficiency by sampling ...
Daniele Moroni   +3 more
core   +2 more sources

On the kinetics of the hydrogen evolution reaction on zinc in sulfate solutions [PDF]

open access: yesJournal of the Serbian Chemical Society, 2001
The kinetics and mechanism of the hydrogen evolution reaction (her) were studied on zinc in 1.0 mol dm-3 Na2SO4 at 298 K, in the pH range 4.4 – 10.
M. VOJNOVIC   +3 more
doaj   +3 more sources

Vibrational deactivation on chemically reactive potential surfaces: An exact quantum study of a low barrier collinear model of H + FH, D + FD, H + FD and D + FH [PDF]

open access: yes, 1980
We study vibrational deactivation processes on chemically reactive potential energy surfaces by examining accurate quantum mechanical transition probabilities and rate constants for the collinear H + FH(v), D + FD(v), H + FD(v), and D + FH(v) reactions ...
Kuppermann, Aron, Schatz, George C.
core   +1 more source

On the existence of Hopf bifurcations in the sequential and distributive double phosphorylation cycle [PDF]

open access: yes, 2019
Protein phosphorylation cycles are important mechanisms of the post translational modification of a protein and as such an integral part of intracellular signaling and control. We consider the sequential phosphorylation and dephosphorylation of a protein
Conradi, Carsten   +2 more
core   +2 more sources

Gas Phase Oxidation of Carbon Monoxide by Sulfur Dioxide Radical Cation: Reaction Dynamics and Kinetic Trend With the Temperature

open access: yesFrontiers in Chemistry, 2019
Gas phase ion chemistry has fundamental and applicative purposes since it allows the study of the chemical processes in a solvent free environment and represents models for reactions occurring in the space at low and high temperatures.
Daniele Catone   +7 more
doaj   +1 more source

Rate constants measured for hydrated electron reactions with peptides and proteins [PDF]

open access: yes, 1968
Effects of ionizing radiation on the amino acids of proteins and the reactivity of the protonated amino group depends upon the pK subscript a of the group.
Braams, R.
core   +1 more source

Universal rate constants for reactive collisions of ultracold molecules

open access: yes, 2010
A simple quantum defect model gives analytic expressions for the complex scattering length and threshold collision rates of ultracold molecules. If the probability of reaction in the short-range part of the collision is high, the model gives universal ...
Idziaszek, Zbigniew, Julienne, Paul S.
core   +1 more source

Changes in Body Composition in Children and Young People Undergoing Treatment for Acute Lymphoblastic Leukemia: A Systematic Review and Meta‐Analysis

open access: yesPediatric Blood &Cancer, EarlyView.
ABSTRACT Ongoing evidence indicates increased risk of sarcopenic obesity among children and young people (CYP) with acute lymphoblastic leukemia (ALL), often beginning early in treatment, persisting into survivorship. This review evaluates current literature on body composition in CYP with ALL during and after treatment.
Lina A. Zahed   +5 more
wiley   +1 more source

Thermokinetic study on the inactivation reactions of 1-methylphthalazinium ylids [PDF]

open access: yesJournal of the Serbian Chemical Society, 2003
The present paper consists in a thermokinetic study on the dimerization reactions of 1-methylphthalazinium ylids with –NO2 (ylid 1) and, respectively, –O–CH3 (ylid 2) substituents in the p position of the benzoyl radical bound to the ylidic carbanion ...
MAGDA PETROVANU   +4 more
doaj  

Home - About - Disclaimer - Privacy