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In-situ reductive dehalogenation [PDF]
, 2018 This master thesis is focused on groundwater remediation of chlorinated ethylenes and methanes in the area of chemical factory Spolchemie in the Czech Republic, Ústí nad Labem city. For these purposes nano zero valent iron particles were used.
Dvořák, Petr
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Reductive Dehalogenation of 2-Aminochloropyrimidine
YAKUGAKU ZASSHI, 1950 Masao Ishikawa, Hideo Kano
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Reductive Dehalogenation of Halogenated Aliphatic and Aromatic Organic Compounds with Metals.
, 2007 The aim of this contribution is to supply information about the feasibility of reductive dehalogenation of selected pollutants (4-chlorophenol, PCB, PBDE, 1,2-dichloro ethane, vinylchloride) in synthetic and real waters on experiments in laboratory scale
Kaštánek, František
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Editorial: Microorganisms in dehalogenation: regulation and enhancement
Frontiers in MicrobiologyGuofang Xu, Honghong Lyu, Jingchun Tang
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Critical Role of Semiquinones in Reductive Dehalogenation
Environmental Science & Technology, 2023 Quinones and products of their redox reactions (hydroquinones and semiquinones) have been suggested as important players in the reductive dehalogenation of organohalogens mediated by natural and pyrogenic organic matter, although based on limited direct evidence. This study focused on the reductive dehalogenation of a model organohalogen (triclosan) by
Srinidhi Lokesh +3 more
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Biochemistry of Catabolic Reductive Dehalogenation
Annual Review of Biochemistry, 2017 A wide range of phylogenetically diverse microorganisms couple the reductive dehalogenation of organohalides to energy conservation. Key enzymes of such anaerobic catabolic pathways are corrinoid and Fe–S cluster–containing, membrane-associated reductive dehalogenases.
Maeva, Fincker, Alfred M, Spormann
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Anaerobic Reductive Dehalogenation of Polychlorinated Dioxins
Applied Microbiology and Biotechnology, 2009Polychlorinated dibenzo-p-dioxins and -furans (PCDD/Fs) are among the most harmful environmental contaminants. Their widespread distribution due to unintentional or unknown release coincides with environmental persistence, acute and chronic toxicity to living organisms, and long-term effects due to the compounds' tendency for bioaccumulation and ...
Michael Bunge, Ute Lechner
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Tetrahedron, 2000 International audienceSubnanometric Ni–Al clusters, in situ prepared by reduction of equimolar amounts of Ni(OAc)2 and Al(Acac)3 induced by alkoxide activated sodium hydride, exhibit a high catalytic activity for efficient reductive dehalogenation of ...
Fabien Massicot +2 more
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Mechanism of Cobalamin-Mediated Reductive Dehalogenation of Chloroethylenes [PDF]
ACS Catalysis, 2017 Reductive dehalogenation involvingcobalamin has been proved to be a promising strategy for decontamination of the polluted environment. However, cob(I)alamin can act both as a strong reductant and a powerful nucleophile, and thus, several competing ...
Li Ji, Piotr Paneth, Kasper P. Kepp
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The stereochemistry of reductive dehalogenation
Tetrahedron, 1968Abstract The stereochemistry of reductive dehalogenation has been examined employing three representative reducing agents—zinc and acetic acid, chromous acetate, and catalytic hydrogenation over Pd C. Chromous acetate and zinc and acetic acid reduce, in greater than 70% yield, just the chlorine atom anti to the double bond in the title compound ...
K.L. Williamson +2 more
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