Results 61 to 70 of about 8,405 (234)

Biomass-supported catalysts on Desulfovibrio desulfuricans and Rhodobacter sphaeroides [PDF]

, 2008
A Rhodobacter sphaeroides-supported dried, ground palladium catalyst (‘‘Rs-Pd(0)’’) was compared with a Desulfovibrio desulfuricans-supported catalyst (‘‘Dd-Pd(0)’’)and with unsupported palladium metal particles made by reduction under H2 (‘‘Chem-Pd(0)’’)
Baxter-Plant, VS, Deplanche, K, Macaskie, LE, Redwood, MD   +3 more
core  

SmI2/Sm‐Induced Reductive Silacyclization of Alkene/Diene Derivatives Using Dichlorosilanes or 1,2‐Dichlorodisilanes via Reductive Radical‐Polar Crossover

Chemistry – A European Journal, EarlyView.
A SmI2/Sm‐mediated silacyclization unlocks a concise route to 4–7‐membered silacycles from simple unsaturated substrates and dichlorosilanes/disilanes. The complementary functions of samarium reductants trigger a reductive radical–polar crossover, offering a versatile strategy for constructing multiple Si─C bonds efficiently.
Zhengwei Chen, Daigo Kondo, Tsutomu Mizota, Leo Onishi, Huiying Mu, Koji Miki, Akiya Ogawa, Kouichi Ohe   +7 more
wiley   +1 more source

Radical Carbon–Carbon Bond Formations Enabled by Visible Light Active Photocatalysts

CHIMIA, 2012
This mini-review highlights the Stephenson group's contribution to the field of photoredox catalysis with emphasis on carbon–carbon bond formation.
Carl-Johan Wallentin, John D. Nguyen, Corey R. J. Stephenson   +2 more
doaj   +1 more source

Carbonylative Suzuki–Miyaura Coupling of 1‐Iodoglycals Mediated by the N‐Heterocyclic Carbene Catalyst PEPPSI: Preparation of C‐Acyl Glycosides

European Journal of Organic Chemistry, EarlyView.
A multicomponent carbonylative Suzuki–Miyaura reaction was developed for the synthesis of C‐acyl glycosides. Using Pyridine‐Enhanced Precatalyst Preparation, Stabilization, and Initiation (PEPPSI‐IPr) catalysis and Mo(CO)6 as a solid CO source, the reaction enables selective carbonylation of three components in synthetically useful yields, providing a ...
Eurípedes de Aguiar, Mônica F. Z. J. Toledo, Flávia Manarin, João H. de Araujo‐Neto, Milene M. Hornink, Hélio A. Stefani   +5 more
wiley   +1 more source

Dehalococcoides as a Potential Biomarker Evidence for Uncharacterized Organohalides in Environmental Samples

Frontiers in Microbiology, 2017
The massive production and improper disposal of organohalides resulted in worldwide contamination in soil and water. However, their environmental survey based on chromatographic methods was hindered by challenges in testing the extremely wide variety of ...
Qihong Lu, Ling Yu, Zhiwei Liang, Qingyun Yan, Zhili He, Tiangang Luan, Dawei Liang, Shanquan Wang, Shanquan Wang   +8 more
doaj   +1 more source

Recent Advances in Conjugated Microporous Polymers for Photocatalysis: Mechanism, Synthesis and Applications

Exploration, EarlyView.
Conjugated microporous polymers (CMPs) have attracted more and more attention as new photocatalysts due to their unique advantages such as high performance, long stability and strong light absorption. This review summarizes the application of CMPs as a photocatalyst in recent years and introduces the catalytic mechanism.
Dun Zhou, Kongqing Zhang, Xiaobai Li, Yongpeng Liu, Liang Yao, Hongwei Ma   +5 more
wiley   +1 more source

Microbial Community Changes in a Chlorinated Solvents Polluted Aquifer Over the Field Scale Treatment With Poly-3-Hydroxybutyrate as Amendment

Frontiers in Microbiology, 2018
This study investigated the organohalide-respiring bacteria (OHRB) and the supporting microbial populations operating in a pilot scale plant employing poly-3-hydroxybutyrate (PHB), a biodegradable polymer produced by bacteria from waste streams, for the ...
Bruna Matturro, Lucia Pierro, Emanuela Frascadore, Marco Petrangeli Papini, Simona Rossetti   +4 more
doaj   +1 more source

Remediation of chlorinated aliphatic hydrocarbons (CAHs) contaminated site coupling groundwater recirculation well (IEG-GCW®) with a peripheral injection of soluble nutrient supplement (IEG-C-MIX) via multilevel-injection wells (IEG-MIW)

Heliyon, 2022
An innovative Groundwater Circulation Well (GCW) process was configured, installed, and tested for optimizing the distribution of a soluble nutrient supplement in a heterogeneous aquifer for reductive dehalogenation.
Paolo Ciampi, Carlo Esposito, Ernst Bartsch, Eduard J. Alesi, Gert Rehner, Marco Petrangeli Papini   +5 more
doaj   +1 more source

Transannular O‐Heterocyclization Reactions of Cyclododeca‐1,5,9‐triene Derivatives: A New Concept for the Preparation of Key Intermediates for Total Syntheses of Annonaceous Acetogenins

Helvetica Chimica Acta, EarlyView.
Four stereogenic centers are formed diastereoselectively in one step from a cyclic (E,E)‐1,5‐diene system using an electrophilic addition reaction. Subsequent ozonolytic cleavage of the intact Z‐double bond, followed by intramolecular nucleophilic substitution, yields an octahydroterfurandione with a threo,cis,threo configuration, an arrangement found ...
Holger Schimanski, André Streiter, Micheline May, Oliver Mimkes, Johannes van Kempen, Constantin Daniliuc, Günter Haufe   +6 more
wiley   +1 more source

Presence, Diversity, and Enrichment of Respiratory Reductive Dehalogenase and Non-respiratory Hydrolytic and Oxidative Dehalogenase Genes in Terrestrial Environments

Frontiers in Microbiology, 2019
Organohalide-respiring bacteria have been linked to the cycling and possible respiration of chlorinated natural organic matter (Cl-NOM) in uncontaminated soils and sediments. The importance of non-respiratory hydrolytic/oxidative dechlorination processes
Hanna R. Temme, Aaron Carlson, Paige J. Novak   +2 more
doaj   +1 more source