Results 131 to 140 of about 45,362 (276)

Remote Migratory Reductive Arylation of Unactivated Alkenes Enabled by Electrochemical Nickel Catalysis

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
we have developed an electrochemical Ni−H catalyzed arylation coupling method of unactivated alkenes with aryl halides. The method displays broad functional group tolerance and proceeds under very mild conditions. Furthermore, aryl chlorides were also compatible substrates in this catalytic system. This conversion holds significant implications for the
Chao Xu, Ru‐Han A, Xiao‐Feng Wu
wiley   +1 more source

Catalyst-Controlled, Regiodivergent Aminooxygenation Reactions of Dienes. [PDF]

J Org Chem
McNichol CP, Borrego L, Ertekin E, Paradine SM.   +3 more
europepmc   +1 more source

Regioselective Iridium-Catalyzed Asymmetric Monohydrogenation of 1,4-Dienes

, 2017
Jianguo Liu, Suppachai Krajangsri, Thishana Singh, Giulia De Seriis, Napasawan Chumnanvej, Haibo Wu, Pher G. Andersson   +6 more
openalex   +2 more sources

Electrochemical Three‐Component Synthesis of Vinyl Sulfonamides via Decarboxylative Sulfonylation of Cinnamic Acids

ChemSusChem, EarlyView.
An efficient, metal‐free electrochemical three‐component reaction of cinnamic acids, SO2, and amines to access (E)‐β‐styryl sulfonamides is reported. Utilizing graphite electrodes and SO2 stock solutions, this decarboxylative protocol proceeds under mild conditions with high regio‐ and stereoselectivity.
Po‐Chung Chien, Harald Kelm, Georg Manolikakes   +2 more
wiley   +1 more source

Chiral poly(aza-norbornene) derivatives with tunable tacticity and living ROMP capability. [PDF]

Chem Sci
Bai J, Wang Y, Wang Y, Zhang N, Wang X, Xu Y, You W.   +6 more
europepmc   +1 more source

Iron‐Catalyzed Regioselective Borobenzylation of Vinyl Arenes [PDF]

Deyuan Meng, Jaesook Yun
openalex   +1 more source

Dinuclear Rhodium(I)–N‐Heterocyclic Carbene Complexes as Alkyne Hydropyridonation Catalysts

European Journal of Inorganic Chemistry, EarlyView.
Catalyst Improvement by NHC tuning: A series of new RhI–NHC dinuclear complexes has been revealed as efficient alkyne hydropyridonation catalysts. 333053IMes complex displays the highest reactivity of the series, suggesting that a moderate steric demand combined with balanced σ‐donation facilitates precatalyst activation and substrate exchange.
Belinda Español‐Sánchez, Mert Olgun Karataş, Andrea Di Giuseppe, Ulugbek Togaev, Vincenzo Passarelli, Luis A. Oro, Jesús J. Pérez‐Torrente, Ricardo Castarlenas   +7 more
wiley   +1 more source

Ring Formation in Sesquiterpene Synthesis: Biomimetic vs. Non‐Biomimetic Strategies

European Journal of Organic Chemistry, EarlyView.
A short review of cyclase enzyme‐mediated ring formation in sesquiterpene biosynthesis is presented as a prelude to six case studies examining the merits and demerits of biomimetic vs. non‐biomimetic strategies for carbocyclisation in the total synthesis of this iconic natural product class.
Bohan Lin, Chen Dai, Alan C. Spivey
wiley   +1 more source

Phosphoramidate and Silyl Amine Mediated Synthesis of Isocyanide Cyclopentadienone Iron Complexes

Helvetica Chimica Acta, EarlyView.
Carbonyl ligands in cyclopentadienone iron complexes are replaced by isocyanide ligands without using free, malodorous isocyanides. The reaction takes place via an Aza‐Wittig‐type reaction starting from primary amines, employing either phosphoramidates or silyl amines as intermediate reagents.
André Bütikofer, Daniel Svoboda, Joël Landis, Peter Chen   +3 more
wiley   +1 more source

Mechanochemical ligand-controlled regiodivergent hydroarylation of alkenes via iron-catalyzed C-H activation. [PDF]

Nat Commun
Zhang ZJ, Liu Z, Chen X, Ackermann L.
europepmc   +1 more source