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regioselectivity (regioselective) [PDF]
, 2014 Citation: 'regioselectivity (regioselective)' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.R05243 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms ...
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Nature Communications, 2019 A key difficulty to overcome in pyridinium salts functionalization is the regioselectivity at the two competing C2 and C4 sites. Here, the authors show bifunctional N-aminopyridinium salts reagents delivering both the aminyl radical and the pyridyl group
Yonghoon Moon +7 more
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Metal-Free Regiodivergent Addition of Carbon Nucleophiles to α,β-Unsaturated Electrophiles
Molecules, 2017 A mild and metal-free regiodivergent addition of carbon nucleophiles to α,β-unsaturated electrophiles was developed. Total 1,2-regioselectivity was observed in the addition of nitrobenzyl chloride derivative 1 to α,β-unsaturated aldehydes 2 in the ...
Cédric Spitz +3 more
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New Regioselective Intercalation Reactions
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 2000 Abstract The ordered layered double hydroxide, [LiA12(OH)6]CI. 2H2O exhibits shape-selective ion-exchange intercalation of dicarboxylate anions. Specific isomeric preferences can be controlled by varying the reaction temperatures. The intercalated guests can be quantitatively recovered from the host lattice with concomitant regeneration of the host ...
O'Hare, D, Fogg, A, Green, V, Harvey, H
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Regioselective Reduction of β‐Enaminoesters
Synthetic Communications, 2005 AbstractFor Abstract see ChemInform Abstract in Full Text.
Hussaini, SR, Moloney, M
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Beilstein Journal of Organic Chemistry, 2017 The condensation of 5-alkoxycarbonyl-1H-pyrrolediones with cyclic ketazinones was systematically investigated. It was discovered that the regioselectivity of this reaction can be easily swapped between two alternative directions affording derivatives of ...
Alexey Yu. Dubovtsev +3 more
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Organics, 2022 The [3+2] cycloaddition reaction of N-aryl-C-carbamoylnitrone (nitrone 1) with N-arylitaconimide (ethylene 2) was computationally studied using the B3LYP/6-31G(d) level of theory. An analysis of the different energetic profiles and the transition states’
Abdelmalek Khorief Nacereddine +1 more
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Strain‐Activated Photo‐Dehalogenation Unlocks Low‐Energy One and Two‐Photon 3D Microfabrication
Advanced Functional Materials, EarlyView.5,14‐NMI‐Cz acts, conversely to its 7,10‐NMI‐Cz(7,10‐'dibromo‐2‐(2,6‐diisopropylphenyl)‐1H‐benzo[lmn]carbazolo[9,1‐bc][2,8]phenanthroline‐1,3(2H)‐dione) counterpart, as modular photoinitiator with panchromatic photoactivity, featuring a weak C–Br bond from geometric strain for efficient Type I & II initiation. These studies demonstrate applicability of
Kacper Piskorz +10 more
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Molecules, 2023 A method for the technically easy-to-implement synthesis of deuterium-labeled pyrazolo[1,5-a]pyrimidines and 1,2,4-triazolo[1,5-a]pyrimidines have been developed. The regioselectivity of such transformations has been shown.
Gevorg G. Danagulyan +3 more
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Advanced Functional Materials, EarlyView.Well‐structured graphene hybrid architectures featuring spatially resolved fluorescent properties represent a promising but so‐far elusive synthetic target. A robust and straightforward method for fabricating well‐organized graphene‐dye hybrid nanoassemblies through a combination of reductive patterning and conventional click chemistry is presented ...
Sabrin Al‐Fogra +12 more
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