Homogeneous and Functional Group Tolerant Ring-Closing Metathesis for DNA-Encoded Chemical Libraries. [PDF]
Monty OBC +6 more
europepmc +1 more source
Bidirectional Synthesis of the IJK Fragment of Ciguatoxin CTX3C by Sequential Double Ring-Closing Metathesis and Tsuji-Trost Allylation. [PDF]
Popadynec M, Gibbard H, Clark JS.
europepmc +1 more source
Chelation‐Assisted Metal‐Catalyzed Ligation and Cleavage Reactions for Chemical Biology
Chelation‐assisted transition metal catalysis has emerged as a promising complement to bioorthogonal click chemistry for studying biological processes. By pre‐organizing catalytic metal centers, designed coordinating substrates enhance reactivity and biocompatibility, enabling site‐selective ligation and decaging reactions in complex biological media ...
Emilie Plantiveau +3 more
wiley +1 more source
Construction of quaternary stereocenters via Ru-catalyzed asymmetric ring-closing metathesis. [PDF]
Li S +9 more
europepmc +1 more source
"Close-to-Release": Spontaneous Bioorthogonal Uncaging Resulting from Ring-Closing Metathesis. [PDF]
Sabatino V, Rebelein JG, Ward TR.
europepmc +1 more source
Synthesis of Substituted Tetrafluorocyclobutenes and Their Ring-Opening Metathesis/Ring-Closing Metathesis to Dihydrofurans Bearing a Tetrafluoroethylene Unit. [PDF]
Kučnirová K +3 more
europepmc +1 more source
Programmable Artificial-Cellular Membrane Dynamics via Ring-Closing Metathesis. [PDF]
Hamaguchi R +3 more
europepmc +1 more source
Amide‐Enabled Reversal of Regioselectivity in Carbonyl‐Substituted Allenes
A substrate‐embedded secondary amide reverses the inherent regioselectivity of carbonyl‐substituted allenes, enabling rhodium‐catalyzed α‐acyloxylation with carboxylic acids. This redox‐neutral method requires no external oxidants or auxiliary‐type directing groups and tolerates diverse carboxylic acids.
Naoki Hikida +3 more
wiley +1 more source
Efficient convergent synthesis of 1,3-diazepinone nucleosides by ring-closing metathesis and direct glycosylation. [PDF]
Hedger AK +5 more
europepmc +1 more source
Synthesis and Polymerization of a Lactone Building Block Derived From Cashew Nut Shells
Cardanol as a renewable substituted phenol feedstock was selectively transformed into the corresponding cyclohexanone derivative by means of a partial metal‐catalyzed hydrogenation. Subsequent conversion via Baeyer–Villiger oxidation gave a lactone product consisting of a mixture of regioisomers, which has been readily converted into its homopolymer ...
Paulo R. Wohlfahrt +6 more
wiley +1 more source

