It may seem counterintuitive to first target a ruthenium alkylidyne when Grubbs‐type ruthenium carbene complexes are the actual goal. In the end, however, this tactic pays valuable dividends in terms of practicality, atom economy, flexibility as well as safety: the new route provides ready access to a large assortment of catalysts for alkene metathesis
Mingxu Cui, Alois Fürstner
wiley +2 more sources
A sequential esterification-ring closing metathesis-Nozaki-Hiyama-Kishi strategy for constructing a natural product-like library of tetrahydrofuran-containing macrolides. [PDF]
Driedger D, Wilson DM, Britton R.
europepmc +1 more source
Synthesis of a Carbon‐Linked Acyldepsipeptide Derivative
The synthesis of a methylene‐linked acyldepsipeptide (ADEP) is reported. Success relied upon an improve method to generate a versatile vinyl glycine methyl ester synthon and a rationally optimized Grubb’s metathesis. NMR and in silico studies revealed an unusual trans–trans proline orientation for this new unnatural ADEP analog, advancing the ...
Katelyn G. Stevens-Davis +6 more
wiley +1 more source
Functionalizable Stereocontrolled Cyclopolyethers by Ring-Closing Metathesis as Natural Polymer Mimics. [PDF]
Alkattan M, Prunet J, Shaver MP.
europepmc +1 more source
Recent advances in the application of ring-closing metathesis for the synthesis of unsaturated nitrogen heterocycles. [PDF]
Groso EJ, Schindler CS.
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Fluorinated poly(pyridyl)borates have been utilized to stabilize rhodium‐diene complexes and as supporting ligands in rhodium‐catalyzed redox‐neutral C–C silylation of cyclopropyl acetates, producing silicon‐containing heterocyclic products, dioxasilolanes.
Vo Quang Huy Phan +3 more
wiley +1 more source
Depolymerization of vulcanized poly(cyclopentene), poly(norbornene-ran-cyclopentene) and poly(endo-dicyclopentadiene-ran-cyclopentene) rubbers via ring-closing metathesis depolymerization for monomer recycling. [PDF]
Hayano S +4 more
europepmc +1 more source
Ring-closing-metathesis-based synthesis of annellated coumarins from 8-allylcoumarins. [PDF]
Schultze C, Schmidt B.
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Back to the Electrofuture: Named Reactions Powered by Electroorganic Syntheses
Bridging classical named reactions with modern electroorganic chemistry, this review presents how electrochemical strategies can revive and reinterpret historically significant transformations, highlighting their emerging potential as sustainable alternatives in contemporary organic synthesis.
Debajit Maiti +4 more
wiley +1 more source
Synthetic Approach to the ABCD Ring System of Anticancer Agent Fredericamycin A via Claisen Rearrangement and Ring-Closing Metathesis as Key Steps. [PDF]
Kotha S, Cheekatla SR, Fatma A.
europepmc +1 more source

