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Strain Release Chemistry of Photogenerated Small‐Ring Intermediates [PDF]

open access: yesChemistry - A European Journal, 2021
AbstractPhotochemical processes, such as isomerizations and cycloadditions, have proven to be very useful in the construction of highly strained molecular frameworks. Photoinduced ring strain enables subsequent exergonic reactions which do not require the input of additional chemical energy and provides a variety of attractive synthetic options leading
Till Opatz
exaly   +4 more sources

Efficient ring perception for the Chemistry Development Kit [PDF]

open access: goldJournal of Cheminformatics, 2014
The Chemistry Development Kit (CDK) is an open source Java library for manipulating and processing chemical information. A key aspect in handling chemical structures is the determination of the chemical rings. The rings of a structure are used areas including descriptors, stereochemistry, similarity, screening and atom typing. The CDK includes multiple
John W. May, Christoph Steinbeck
openalex   +4 more sources

Christmas Symposium Basel, December 4, 2020

open access: yesCHIMIA, 2021

Daniel Joss   +9 more
doaj   +1 more source

Put a ring on it: application of small aliphatic rings in medicinal chemistry

open access: yesRSC Medicinal Chemistry, 2021
Aliphatic small rings including cyclopropanes, cyclobutanes, oxetanes, azetidines and bicyclo[1.1.1]pentanes have been increasingly exploited in medicinal chemistry. This review summarises judicious successful application and reported limitations of these ring systems.
Matthias R. Bauer   +6 more
openaire   +3 more sources

Operando CO Infrared Spectroscopy and On-Line Mass Spectrometry for Studying the Active Phase of IrO2 in the Catalytic CO Oxidation Reaction

open access: yesInorganics, 2023
We combine operando diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) with on-line mass spectrometry (MS) to study the correlation between the oxidation state of titania-supported IrO2 catalysts (IrO2@TiO2) and their catalytic activity
Phillip Timmer   +3 more
doaj   +1 more source

XXXI.—Contribution to the chemistry of “Fairy Rings.” [PDF]

open access: yesJ. Chem. Soc., Trans., 1883
n ...
Lawes, J. B.   +2 more
openaire   +2 more sources

Catalytic Cascade Reactions Inspired by Polyketide Biosynthesis

open access: yesCHIMIA, 2020
Aldol reactions belong to the most important methods for carbon–carbon bond formation and are also involved in one of the most astonishing biosynthetic processes: the biosynthesis of polyketides governed by an extraordinarily sophisticated enzymatic ...
Daniel Moser   +6 more
doaj   +1 more source

Characterization of Cysteine Cathepsin Expression in the Central Nervous System of Aged Wild-Type and Cathepsin-Deficient Mice

open access: yesApplied Sciences, 2022
The association of cathepsin proteases in neurobiology is increasingly recognized. Our previous studies indicated that cathepsin-K-deficient (Ctsk−/−) mice have learning and memory impairments.
Denise M. T. Yu   +6 more
doaj   +1 more source

Oxetanes: Recent Advances in Synthesis, Reactivity and Medicinal Chemistry [PDF]

open access: yes, 2016
The 4-membered oxetane ring has been increasingly exploited for its behaviors, i.e. influence on physicochemical properties as a stable motif in medicinal chemistry, and propensity to undergo ring opening reactions as a synthetic intermediate.
Bull, JA   +4 more
core   +1 more source

A Unified Mechanism on the Formation of Acenes, Helicenes, and Phenacenes in the Gas Phase. [PDF]

open access: yes, 2020
A unified low-temperature reaction mechanism on the formation of acenes, phenacenes, and helicenes-polycyclic aromatic hydrocarbons (PAHs) that are distinct via the linear, zigzag, and ortho-condensed arrangements of fused benzene rings-is revealed. This
Ablikim, Utuq   +8 more
core   +1 more source

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