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Chemistry of the Natural Rotenoids
1963In many warm countries of the world the natives fish by throwing preparations of crushed plant material into ponds and streams. These preparations cause stupefaction of the fish, which rise to the surface and are collected. Plants which are frequently employed in South America, tropical Africa, the East Indies and Malaya belong to the Papilionatae sub ...
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Rotenoids from Amorpha canescens
Transactions of the Kansas Academy of Science (1903-), 1979recovered no rotenoids. Elution (6-8 column volumes) with 1:3 EtOAc/hexane recovered all rotenoid materials. The solvent was evaporated and the residue analyzed by TLC (Delfel, 1966) and HPLC (Moring, 1977). Direct comparison with standards suggested the presence of rotenone, degulin, tephrosin, and rotenolone. Peaks with retention volumes of rotenone,
Stephen E. Moring, James D. McChesney
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Journal of the Chemical Society D: Chemical Communications, 1971
Insertion of the rotenoid ‘extra’ C-6 methylene occurs at the isoflavone (IIIa), rather than the isoflavanone (IVa), level of oxidation, in the biosynthesis of amorphigenin; earlier stages use chalcone (Va) with a free 4-hydroxy-group, but the biosynthetically acceptable isoflavone which emerges is not (VIa) but its methyl ether (VIb).
L. Crombie, P. M. Dewick, D. A. Whiting
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Insertion of the rotenoid ‘extra’ C-6 methylene occurs at the isoflavone (IIIa), rather than the isoflavanone (IVa), level of oxidation, in the biosynthesis of amorphigenin; earlier stages use chalcone (Va) with a free 4-hydroxy-group, but the biosynthetically acceptable isoflavone which emerges is not (VIa) but its methyl ether (VIb).
L. Crombie, P. M. Dewick, D. A. Whiting
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Rotenoids and Isoflavones fromSarcolobus globosus
Planta Medica, 2005Sarcolobus globosus is a medicinal plant growing in mangrove forests in Asia. No constituents from this plant have been reported previously. From the diethyl ether extract of S. globosus a new rotenoid sarcolobin and a new isoflavone sarcolobone, as well as the previously known rotenoids tephrosin, 12aalpha-hydroxydeguelin, 11-hydroxytephrosin, 12a ...
Helle, Wangensteen +4 more
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Antiinflammatory activity of rotenoids from Clitoria fairchildiana
Phytotherapy Research, 2002Five structurally related rotenoids were isolated from the roots of Clitoria fairchildiana. The antiinflammatory activity was investigated using a capillary permeability assay. The protective effect was measured as the inhibition in vascular permeability produced by acetic acid in the peritoneal cavity. The results suggest that for maximum activity the
Bernadete, Pereira da Silva +1 more
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Rotenoid synthesis via radical cyclisation
Journal of the Chemical Society, Chemical Communications, 1988The (±)-6aα, 12aα, 12α-chromanochromanol acetate (11; R = Ac), representing the core structure of the insecticidal rotenoid alcohol (2), has been synthesised in six steps from the chromone (4); the cis,cis-stereochemistry is obtained in an intramolecular 6-exo aryl radical addition.
S. Asiah Ahmad-Junan, Donald A. Whiting
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Present Status of Rotenone and Rotenoids
Journal of Economic Entomology, 1941One of the most amazing developments in American agriculture during the past decade has been the rapid growth in the use of derris, cube, timbo, and barbasco as insecticides. These plants, all closely related botanically and belonging to the family Fabaceae, owe their toxicity to rotenone and a group of structurally related compounds called rotenoids.
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Rotenoid diversity, distribution and evolution in plant lineages
Natural Product ReportsThis highlight revisits rotenoid classification and provides a thorough understanding of how their occurrences could inform plant taxonomy.
Vaderament-A. Nchiozem-Ngnitedem +2 more
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[Rotenoids from Derris trifoliata].
Zhong yao cai = Zhongyaocai = Journal of Chinese medicinal materials, 2008Five rotenoids named dehydrodeguelin, dehydrorotenone, 12a-hydroxy rotenone, tephrosin and 12alphabeta-hydroxyrot-2'-enonic acid were isolated from aerial parts of Derris trifoliata. All these compounds were isolated from this plant for the first time.
Lu-Rong, Xu +3 more
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Reaction of Rotenoids with Hydrazine
HETEROCYCLES, 1986Ivanka Kostova +4 more
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