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Synthesis, Characterization, and Biological Activity of New 4'-Functionalized Bis-Terpyridine Ruthenium(II) Complexes: Anti-Inflammatory Activity Advances. [PDF]
Elnagar MM +5 more
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Strongly luminescing ruthenium(II)/ruthenium(II) and ruthenium(II)/platinum(II) binuclear complexes
Inorganic Chemistry, 1986Two strongly luminescing complexes, ruthenium(II)/ruthenium(II) homobinuclear complex and ruthenium(II)/platinum(II) heterobinuclear complex, have been prepared and characterized. The organic part of the complex is 4,4'-dimethyl-2,2' bipyridine dimer.
Ram Sahai +2 more
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Oxygenation of a Ruthenium(II) Thiolate to a Ruthenium(II) Sulfinate Proceeds via Ruthenium(III)
Inorganic Chemistry, 2005Exposure of acetonitrile/methanol solutions of [PPN][Ru(DPPBT)3] [PPN = bis(triphenylphosphoranylidene); DPPBT = 2-diphenylphosphinobenzene thiolate] to oxygen initiates metal-centered oxidation, yielding the ruthenium(III) thiolate Ru(DPPBT)3. Ru(DPPBT)3 further reacts with oxygen, at sulfur, to give the ruthenium(III) sulfinate complex [Ru(DPPBT-O2)2(
Craig A, Grapperhaus +2 more
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Inorganic Chemistry, 2023
The study disclosed that the reactivities of [RuII (PPh3)3Cl2] and [RuII(PPh3)3(CO)(H)Cl] precursors toward a trimethoxyarylimino-phenol derivative are sensibly different. The former promotes methoxy demethylation reaction affording a [Phenolato-RuIII-Phenolato] unit, while the latter containing π-acidic CO and hydride as coligands leads to C-H ...
Debasish Samanta +4 more
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The study disclosed that the reactivities of [RuII (PPh3)3Cl2] and [RuII(PPh3)3(CO)(H)Cl] precursors toward a trimethoxyarylimino-phenol derivative are sensibly different. The former promotes methoxy demethylation reaction affording a [Phenolato-RuIII-Phenolato] unit, while the latter containing π-acidic CO and hydride as coligands leads to C-H ...
Debasish Samanta +4 more
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ChemInform, 1987
AbstractThe dimeric bipyridine ligand, prepared by a literature method with a yield of ca. 60%, reacts with a Ru complex, prepared in situ from RuCl2(bipy)2 (bipy: 2,2'‐bipyridine) and acetone in the presence of Ag(O‐SO2‐CF3) at reflux temp. within 5 d to give the new dimer (Ia).
R. SAHAI, D. A. BAUCOM, D. P. RILLEMA
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AbstractThe dimeric bipyridine ligand, prepared by a literature method with a yield of ca. 60%, reacts with a Ru complex, prepared in situ from RuCl2(bipy)2 (bipy: 2,2'‐bipyridine) and acetone in the presence of Ag(O‐SO2‐CF3) at reflux temp. within 5 d to give the new dimer (Ia).
R. SAHAI, D. A. BAUCOM, D. P. RILLEMA
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Electroluminescence in Ruthenium(II) Complexes
Journal of the American Chemical Society, 2002We have investigated the electrochemical, spectroscopic, and electroluminescent properties of a family of diimine complexes of Ru featuring various aliphatic side chains as well as a more extended pi-conjugated system. The performance of solid-state electroluminescent devices fabricated from these complexes using indium tin oxide (ITO) and gold ...
Stefan, Bernhard +6 more
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TETRAETHYLPHYROPHOSPHITE AS A BRIDGING LIGAND IN A BIMETALLIC RUTHENIUM(II) - RUTHENIUM(II) COMPLEX
Journal of Coordination Chemistry, 1984Abstract The complex μ-TEPP-trans-bis[P(OEt)3Ru(NH3)4]2(PF6)4 has been prepared and characterized by microanalysis, vibrational and electronic spectroscopy (λmax=299 nm, ∊=6.4 × 102 M−1 cm−1; λmax=262 nm, ∊=8.6 × 102 M−1 cm−1), and cyclic voltammetry (E°'=+0.64 V versus S.C.E., 25°, μ=0.10 M NaCf3COO, CH+=1 × 10−3 M).
Mário S. Galhiane, Douglas W. Franco
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Aspects of Aqueous Ruthenium(II) Chemistry
Helvetica Chimica Acta, 2001Since the first facile synthesis of [Ru(H2O)(6)](tos)(2) was published at the beginning of the eighties, several Ru-II aqueous inorganic and organometallic complexes were described, showing the increasing interest in this kind of compound due to potential applications in catalysis and medicine.
Grundler, Pascal Vincent +2 more
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Inorganica Chimica Acta, 1988
Abstract The reactions of Ru II OEP(L) 2 and Ru II TPP(L) 2 with carbon monoxide, where OEP and TPP are the dianions of octaethylporphyrin and tetraphenylporphyrin, respectively, are reported for various ligands (L=dimethyl formamide, acetonitrile, aniline and substituted benzonitriles).
Donald R. Paulson +7 more
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Abstract The reactions of Ru II OEP(L) 2 and Ru II TPP(L) 2 with carbon monoxide, where OEP and TPP are the dianions of octaethylporphyrin and tetraphenylporphyrin, respectively, are reported for various ligands (L=dimethyl formamide, acetonitrile, aniline and substituted benzonitriles).
Donald R. Paulson +7 more
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Aniline complexes of ruthenium(II) and ruthenium(III) halides
Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1971The preparations, i.r. and electronic spectra, and magnetic susceptibilities of the ruthenium(III) complexes A[RuX4-(aniline)2](A = Cs, Me4N, C6H5NH3 or C5H6N, and X = Cl, Br, or I); and of the ruthenium(II) complexes [RuL6]Br2 and RuL4Br2(L = a substituted aniline) are reported. From their spectroscopic properties the compounds containing co-ordinated
D. L. Key +2 more
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