Química Nova, 2010 The effects of solvents on chemical phenomena is complex because there are various solute-solvent interaction mechanisms. Solvatochromism refers to the effects of solvents on the spectra of probes. The study of this phenomenon sheds light on the relative
Omar A. El Seoud
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Novel Method for Characterizing Humic Substances Using Fluorescent Solvatochromism [PDF]
SensorsCharge-transfer-type fluorochromes, which exhibit shifts in fluorescence intensity and emission wavelength in response to solvent polarity changes, have been widely employed to investigate solute–solvent interactions. Humic substances (HSs) are naturally
Kazuto Sazawa +6 more
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PET-Driven Fluorescence Modulation in Halochromic Styryl Hemicyanine Dyes Targeting DNA Minor Groove [PDF]
MoleculesA new series of styryl hemicyanine dyes featuring substituted N-phenylpiperazine end groups was synthesized using an environmentally friendly procedure.
Teodora Aleksandrova +5 more
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Real‐Time In Situ Imaging of Aggregation‐Induced Emission and Solvent‐Guided Morphogenesis of a “V‐Shaped” 4‐Amino‐1,8‐Naphthalimide Tröger's Base Supramolecular Scaffold [PDF]
Small ScienceThe influence of solvent polarity on the self‐assembly processes and its effect on the morphological outcome of self‐assembled aggregates is another domain that requires a comprehensive study.
Sankarasekaran Shanmugaraju +6 more
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The UV-Visible Absorption Spectra of Coumarin and Nile Red in Aqueous Solution: A Polarizable QM/MM Study [PDF]
MoleculesWe present a comprehensive computational study of the UV-visible absorption spectra of 7-methoxycoumarin and Nile red in aqueous solution. Our fully atomistic workflow couples classical molecular dynamics (MD) with polarizable QM/MM based on fluctuating ...
Tommaso Giovannini +2 more
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Chromotropism of Iron(II) Complexes with Non-Symmetric Heterocyclic Ligands: Polarity Sensing in Aqueous Urea Solutions [PDF]
NanomaterialsThis study reports the synthesis and characterization of two solvatochromic pentacyanoferrate(II) complexes. Their structural design incorporates ligands with flexible xylylene bridges and distinct heterocycles—one combining 4-dimethylaminopyridine (DMAP)
Raffaello Papadakis
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SOLVATOCROMISMO E AS ESCALAS EMPÍRICAS DE POLARIDADE DO SOLVENTE: UMA REVISÃO [PDF]
Química Nova, 2023 The term solvatochromism is used to describe the changes in the optical properties of a dye molecule by influence of the solvent characteristics. Solvatochromic shifts are governed by intermolecular interactions between solute-solvent that can be either ...
Ingrid Maliszewski Paczkowski +1 more
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Orbital: The Electronic Journal of Chemistry, 2022 This work presents a proposal of experimental activity involving organic synthesis and solvatochromism of an organic molecule, correlating the content of organic chemistry and physical organic chemistry.
Taianne D’Angelo Korb +2 more
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Assessing the pharmacological potential of selected xanthene derivatives [PDF]
Journal of the Serbian Chemical Society, 2023 A convenient and efficient approach toward the synthesis of seven aromatically substituted xanthendiones 1‒7 and one structurally-related xanthenone 8 through condensation of dimedone and the appropriate aromatic aldehyde is reported.
Lazić Anita M. +3 more
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Molecules, 2022 Solvatochromic dyes are utilized in various chemical and biological media as chemical sensors. Unfortunately, there is no simple way to predict the type of solvatochromism based on the structure of the dye alone, which restricts their design and ...
Andrés Aracena, Moisés Domínguez
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