Results 31 to 40 of about 7,506 (232)

Anti-quenching NIR-II molecular fluorophores for in vivo high-contrast imaging and pH sensing

open access: yesNature Communications, 2019
Fluorophores operating in the second near-infrared window suffer from solvatochromism-caused fluorescence quenching in biological aqueous solution. Here, the authors synthesized a series of pH-responsive pentamethine cyanine fluorophores that afford ...
Shangfeng Wang   +7 more
doaj   +1 more source

Design of Promising aza-BODIPYs for Bioimaging and Sensing

open access: yesDesigns, 2022
The obtainment of new luminophores for molecular sensorics of biosystems is becoming one of the urgent tasks in the field of chemical synthesis. The solution to each practical problem imposes its own limitations in the design of new structures with ...
Dmitry Merkushev   +5 more
doaj   +1 more source

On the characterization of NaDEHP/n-heptane nonaqueous reverse micelles: The effect of the polar solvent [PDF]

open access: yes, 2015
The behavior of two polar solvents, ethylene glycol (EG) and dimethylformamide (DMF), entrapped in sodium bis-(2-ethylhexyl) phosphate (NaDEHP)/n-heptane reverse micelles (RMs) was investigated using dynamic light scattering (DLS), molecular probe ...
Chessa, Juana Josefa   +4 more
core   +1 more source

Synthesis of novel multifunctional carbazole-based molecules and their thermal, electrochemical and optical properties

open access: yesBeilstein Journal of Organic Chemistry, 2020
Two novel carbazole-based compounds 7a and 7b were synthesised as potential candidates for application in organic electronics. The materials were fully characterised by NMR spectroscopy, mass spectrometry, FTIR, thermogravimetric analysis, differential ...
Nuray Altinolcek   +5 more
doaj   +1 more source

Synthesis of Novel Aqua ƞ4-NNNO/Cu(II) Complexes as Rapid and Selective Oxidative Catalysts for O-Catechol: Fluorescence, Spectral, Chromotropism and Thermal Analyses

open access: yesCrystals, 2021
A new tetradentate Schiff base (SB), (E)-4-fluoro-2-(1-((2-(piperazin-1-yl)ethyl)imino)ethyl)phenol, was synthesized from condensation of 2-(1-piperazinyl)ethylamine and 5-fluoro-2-hydroxyacetophenone.
Amjad M. Shraim   +5 more
doaj   +1 more source

Novel Fluorescent Probe Based on Anthryl Dendron Having Oligo(ethyleneoxide) Groups at the Terminals [PDF]

open access: yes, 2008
Amphiphilic anthryl dendrons 5 and 6, which have carboxylate groups or oligo(ethyleneoxide) groups at the terminals, show solvatochromic properties. Reaction efficiency of photodimerization and dynamic light scattering (DLS) experiment of 5 and 6 reveal ...
Takaguchi, Yutaka, Yanagimoto, Yasushi
core   +1 more source

Solvatochromism and electrophilicity

open access: yesChemical Physics Letters, 2011
Abstract Solvatochromic dyes that exhibit a negative or a positive behaviour may be distinguished and their solvatochromism predicted with the aid of DFT-based indices, such as their electrophilicity ω , hardness η and by the Fukui electrophilic functions f G + of the donor and acceptor moieties of the molecule, calculated in the ...
Caroli Rezende, Marcos   +3 more
openaire   +4 more sources

A Family of Ethyl N-Salicylideneglycinate Dyes Stabilized by Intramolecular Hydrogen Bonding: Photophysical Properties and Computational Study

open access: yesMolecules, 2021
In this work we report solvatochromic and luminescent properties of ethyl N-salicylideneglycinate (1), ethyl N-(5-methoxysalicylidene)glycinate (2), ethyl N-(5-bromosalicylidene)glycinate (3), and ethyl N-(5-nitrosalicylidene)glycinate (4) dyes.
Larisa E. Alkhimova   +2 more
doaj   +1 more source

Preferential solvation of quercetin in aqueous aprotic solvent mixtures [PDF]

open access: yesJournal of the Serbian Chemical Society, 2020
Solvatochromism of quercetin was studied in binary mixtures of water with dimethyl sulfoxide, N,N-dimethylformamide and N,N-dimethylacetamide at 25 °C by UV–Vis measurements.
Faraji Mohammad, Farajtabar Ali
doaj   +1 more source

A BODIPY-Bridged Bisphenoxyl Diradicaloid: Solvent-Dependent Diradical Character and Physical Properties

open access: yesMolecules, 2019
We report a new boron dipyrromethene (BODIPY)-bridged bisphenoxyl diradicaloid (2), which showed closed-shell diamagnetic character in less polar solvents such as dichloromethane but open-shell diradical character with paramagnetic activity in the very ...
Fang Miao, Hoa Phan, Jishan Wu
doaj   +1 more source

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