Eco conscious synthesis of poly(tetramethylene itaconate) emphasizing inhibitor free and solvent free sustainability [PDF]
Scientific ReportsArtificial tissues and organs can be obtained through a modern material processing method − 3D printing. In this method, 3D printing inks are used. Those are most commonly made of polyacrylates which show several undesirable characteristics.
Magdalena Miętus +3 more
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Solvent-free autocatalytic supramolecular polymerization [PDF]
Nature Materials, 2021 Abstract Solvent-free chemical manufacturing is one of the awaited technologies for addressing an emergent issue of serious environmental pollution. Here, we report "solvent-free autocatalytic supramolecular polymerization (SF-ASP)", where a phthalonitrile derivative with hydrogen-bonding side chains as the monomer is autocatalytically ...
Zhen Chen +9 more
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Solvent‐Free Synthesis of Peptides [PDF]
Angewandte Chemie, 2009 A crush on sweetness ! A novel solvent-free methodology for the synthesis of peptides was developed: the coupling of an urethane protected N-carboxy anhydride (UNCA) of an aminoacid with another aminoacid derivative gave a protected dipeptide in very high yield under ball-milling conditions. The reaction is taking place in the solid state. This solvent-
Declerck, Valérie +3 more
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Predicting the activity coefficients of free-solvent for concentrated globular protein solutions using independently determined physical parameters. [PDF]
PLoS ONE, 2013 The activity coefficient is largely considered an empirical parameter that was traditionally introduced to correct the non-ideality observed in thermodynamic systems such as osmotic pressure.
Devin W McBride, Victor G J Rodgers
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3D Printing of Solvent-Free Supramolecular Polymers
Frontiers in Chemistry, 2021 Additive manufacturing has significantly changed polymer science and technology by engineering complex material shapes and compositions. With the advent of dynamic properties in polymeric materials as a fundamental principle to achieve, e.g., self ...
Harald Rupp, Wolfgang H. Binder
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Enzymatic Kinetics of Solvent-free Esterification with Bio-imprinted Lipase [PDF]
Chemical and Biochemical Engineering Quarterly, 2020 To avoid the use of compounds that burden the environment, a solvent-free enzymatic reaction was the focus of this study. Investigated were the catalytic activities and kinetics of lipases that were pretreated with carboxylic acids for the solvent-free ...
M. Matsumoto, Y. Hasegawa
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Fast microwave-assisted oxidation of 1,4-dihydropyridines with FeCl 3.SiO 2 [PDF]
, 2005 Pyridine derivatives are easily obtained in high yields by microwave-promoted rapid oxidation of the corresponding 1,4-dihydropyridines with ferric chloride hexahydrate and silica gel under solvent-free ...
Alaee, E. +4 more
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Microwave assisted solvent free synthesis of 1,3-diphenylpropenones
Chemistry Central Journal, 2011 Background 1,3-Diphenylpropenones (chalcones) are well known for their diverse array of bioactivities. Hydroxyl group substituted chalcones are the main precursor in the synthesis of flavonoids.
Sarma Jadab C, Kakati Dwipen
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Transdermal delivery of ibuprofen utilizing a novel solvent free pressure sensitive adhesive (PSA) : TEPI® technology [PDF]
, 2017 Purpose The main objective of this present study was the investigation of potential novel transdermal patch technology (TEPI®) delivering ibuprofen as the active pharmaceutical ingredient (API) using a novel poly(ether-urethane)-silicone crosslinked ...
Haddleton, David M. +3 more
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A novel dimethylformamide (DMF) free bar-cast method to deposit organolead perovskite thin films with improved stability [PDF]
, 2016 We report a solvent-free approach to synthesizing organolead perovskites by using solid state reactions to coat perovskite crystals onto Al2O3 or TiO2 nanoparticles followed by addition of terpineol affording perovskite inks.
Arthur Connell +36 more
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