Zero-Potential No-Discharge APCI Combined With pH and Colorimetric Measurements Reveals a Protein-Dependent Change in Albumin Proton Affinity Under Quantum-Dot Patch Exposure. [PDF]
Libertucci M, Spera DM, Orrù G.
europepmc +1 more source
FT-ICR-MS approach to monitor asparagine deamidation and its isomers products in collagen from ancient bones [PDF]
This project investigates the use of ultrahigh resolution mass spectrometry along with fragmentation techniques such as electron capture dissociation (ECD) and collisionally activated dissociation (CAD) to study deamidation of ancient bone, by using ...
Perez Hurtado, Pilar
core
AI‑guided single‑cell transcriptomics identifies OGT as a key regulator enriched in rheumatoid arthritis fibroblast‑like synoviocytes (RA‐FLSs). Inflammatory stimuli activate the OGT–SAP130 axis, which modulates the H3K27ac/H3K27me3 balance and epigenetically silences BTG2, promoting aggressive transformation of RA‑FLSs.
Duoli Xie +14 more
wiley +1 more source
Water‐Derived Radical Species Initiate Six‐Electron Oxidation of Cyclic Ketones in Microdroplets
Spontaneous six‐electron oxidation of cyclic ketones to yield dicarboxylic acids/keto acids is achieved in ethanol microdroplets containing about 2% water under ambient conditions without any metal salts, acids, or oxidants. Mechanistic studies show that trace amounts of water and molecular oxygen serve as active oxidants in this transformation ...
Muhammad Mujahid Ali +3 more
wiley +2 more sources
Enhancing IR-MALDESI MSI Spatial Resolution Through Beam Constriction With a Ring-Actuated Iris. [PDF]
Ashbacher SM +6 more
europepmc +1 more source
Pyrochlore‐derived Bi–Sn interfaces enable selective CO2 electroreduction to HCOOH in strongly acidic media (pH = 1). Interfacial electronic coupling promotes *OCHO formation while suppressing hydrogen evolution. Cryptand‐driven cation regulation enriches interfacial K+, maintaining high HCOOH faradaic efficiency of 94% even at low K+ electrolyte ...
Abdelmoniem H. Abu‐Ghazala +6 more
wiley +1 more source
Structural and Functional Siderophore Remodeling by Enzymatic Delipidation
A surprising functional switch in bacterial siderophores was discovered through genome mining and the analysis of environmental and pathogenic Pandoraea species. Pandorachelin B, a lipocyclopeptide that promotes swarming motility, is cleaved by a specialized acylase, yielding a ring‐contracted, homodetic cyclopeptide, pandorachelin A, which exhibits ...
Elena Herzog +5 more
wiley +2 more sources
Scientific and operational maturity of CE-MS: are we close? [PDF]
Wang D.
europepmc +1 more source
Functional Specialization of Respiratory and Olfactory Mucus Revealed by Proteomic Profiling
ABSTRACT Background Mucus overlies the nasal mucosa in the respiratory and olfactory regions, which perform distinct physiological functions. However, proteomic differences between respiratory mucosa (RM) and olfactory cleft (OC) mucus remain unclear.
Anna Kristina Hernandez +7 more
wiley +1 more source
Gold Clusters With Open‐Shell Ligands: Superatom Mediated Magnetic Interaction
Open‐shell verdazyl radicals were covalently integrated with atomically precise Ir‐doped Au12 (Ir@Au12) superatoms. The resulting radical–superatom hybrids exhibit photoinduced electron transfer, spin delocalization onto the metal‐cluster core, and weak ferromagnetic communication between radicals mediated by the superatomic electronic structure ...
Katsuya Mutoh +7 more
wiley +2 more sources

