An in silico MS/MS library for automatic annotation of novel FAHFA lipids. [PDF]
BackgroundA new lipid class named 'fatty acid esters of hydroxyl fatty acids' (FAHFA) was recently discovered in mammalian adipose tissue and in blood plasma and some FAHFAs were found to be associated with type 2 diabetes.
Fahrmann, Johannes F+5 more
core +2 more sources
A Dual‐Emissive DNA‐Templated Silver Nanocluster with Near‐Infrared I and II Emission
This study presents a dual‐emissive DNA‐stabilized silver nanocluster with a nanosecond‐lived NIR‐I emission band and a microsecond‐lived NIR‐II emission band. Mass spectrometry establishes that the nanocluster has molecular formula (DNA)2[Ag17]11+. DNA sequence variations reveal critical nucleobases for stabilization, and modifications at the DNA 5 ...
Anna Gonzàlez‐Rosell+6 more
wiley +1 more source
Simultaneous sampling of volatile and non-volatile analytes in beer for fast fingerprinting by extractive electrospray ionization mass spectrometry [PDF]
By gently bubbling nitrogen gas through beer, an effervescent beverage, both volatile and non-volatile compounds can be simultaneously sampled in the form of aerosol.
Balabin, Roman+10 more
core
Quantification of voriconazole in plasma by liquid chromatography-tandem mass spectrometry [PDF]
A convenient liquid chromatography-tandem mass spectrometry method for the quantification of the triazole antifungal agent voriconazole in plasma samples is described. Fenbuconazole is used as an internal standard.
Boyd+16 more
core +1 more source
In the presence of a Pd0 catalyst, large π‐extended arynes trimerize in an unusual manner to forge extremely compact and strained chiral benzenoids. This new trimerization reaction involves a 1,7‐Pd isomerization, a rare and poorly understood process that is elucidated.
Albert Artigas+6 more
wiley +1 more source
Structure elucidation of nanogram quantities of unknown designer drugs based on phenylalkylamine derivates by ion trap multiple mass spectrometry [PDF]
Multiple mass spectra (MS1 to MS6) of 55 phenylalkylamine derivatives were recorded with ion-trap mass spectrometry employing electrospray (ESI) and atmospheric pressure chemical ionization (APCI).
Kölliker, Stephan, Oehme, Michael
core
Naphthalimide Derivatives as Film‐Based Fluorescent Sensors for Rapid Detection of Illicit Drugs
Four novel 1,8‐naphthalimide (NI) derivatives for the detection of illicit drugs with different substituents at the 4‐position are reported. Their contrasting fluorescence responses enables five illicit drugs to be distinguished from interferents with a mean classification accuracy of 81%.
Ming Chen+7 more
wiley +1 more source
Rapid method for Mycobacterium tuberculosis identification using electrospray ionization tandem mass spectrometry analysis of mycolic acids [PDF]
Mycolic acids (MAs), which play a crucial role in the architecture of mycobacterial cell walls, were analyzed using electrospray ionization tandem mass spectrometry. A targeted analysis based on the 10 most abundant and characteristic multiple reaction
Beata Janiszewska-Drobinska+38 more
core +1 more source
This study explores polyoxometalate‐based hybrids with varying dimensionalities, linking molecular, polymeric, and framework structures to supercapacitor performance. The results highlight how structural tuning enhances surface area, porosity, and charge transport, offering insights into designing efficient energy storage materials.
Daria Nowicka+6 more
wiley +1 more source
Single-photon absorption of isolated collagen mimetic peptides and triple-helix models in the VUV-X energy range [PDF]
Cartilage and tendons owe their special mechanical properties to the fibrous collagen structure. These strong fibrils are aggregates of a sub-unit consisting of three collagen proteins wound around each other in a triple helix.
Eden, Samuel+9 more
core +5 more sources