Results 121 to 130 of about 138,145 (310)

Structure determination of new algal toxins using NMR methods [PDF]

open access: yes, 2006
Shellfish are considered a delicacy by many consumers. In NZ, as in many overseas countries, there is a now thriv¬ing shellfish industry servicing both domestic and inter-national markets. Periodically shellfish accumulate harm¬ful levels of a variety of
Miles, Christopher O.   +1 more
core  

Effective acetalization of furfural catalyzed by Fe‐ and Co‐oxalates: impact of alcohols structure on products composition

open access: yesBiofuels, Bioproducts and Biorefining, EarlyView.
Abstract Fe‐, Co‐, and FeCo‐oxalates supported on silica gel (5 wt% metal load) were synthesized, characterized, and tested for the first time in solvent‐free furfural (FF) acetalization with C1–C8 alcohols at 70–170 °C under both conventional and microwave (MW)‐assisted conditions. The interaction of FF with linear C1–C4 alcohols yielded pincer‐shaped
Alexander Pokutsa   +3 more
wiley   +1 more source

Regio- and stereochemical stability induced by anomeric and gauche effects in difluorinated pyrrolidines

open access: yesBeilstein Journal of Organic Chemistry
Selective fluorination of the pyrrolidine ring in proline motifs has been found to induce significant conformational changes that impact the structure and biological roles of modified peptides and proteins.
Ana Flávia Candida Silva   +2 more
doaj   +1 more source

Selective N‐Alkylation of Unprotected Amino Sugars by Alcohols. Application to the Synthesis of Sugar‐Based Surfactants

open access: yesChemistryEurope, EarlyView.
A borrowing hydrogen strategy using an NHC‐Ir(III) catalyst enables selective N‐functionalization of unprotected amino sugars using alcohols as alkylating agents. The use of unprotected substrates avoids extra steps of protection/deprotection, minimizing waste generation.
Aitor Bermejo‐López   +7 more
wiley   +1 more source

Imidazoline‐Proline and Imidazoline‐Prolinate Ligands for Copper‐Catalyzed Asymmetric Exo‐Selective [3 + 2] Cycloaddition of Iminoesters with Nitroalkenes

open access: yesChemistryEurope, EarlyView.
From a modular synthesis of nonphosphine chiral nitrogen‐based chiral imidazoline–amino acid ligands, two new chiral imidazoline–proline‐copper catalysts are developed for targeting exo‐selective [3 + 2] cycloaddition reaction. Density functional theory studies rationalize the observed stereoselectivity and the distinct chiral pockets of the two ...
Yan Yu   +4 more
wiley   +1 more source

Stereochemistry of the dTDP-glucose oxidoreductase reaction.

open access: hybrid, 1977
Carl E. Snipes   +4 more
openalex   +1 more source

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